Graphene network enabled high speed electrical actuation of shape memory nanocomposite based on poly(vinyl acetate)

作者: Mohammad Sabzi , Masoud Babaahmadi , Navid Samadi , Gholam Reza Mahdavinia , Mohsen Keramati

DOI: 10.1002/PI.5303

关键词: ScratchNanocompositeMaterials scienceComposite materialGrapheneModulusVinyl acetateElectrical resistivity and conductivityDynamic mechanical analysisShape-memory alloy

摘要: Here strong electroactive shape memory nanocomposites were prepared by incorporating graphene nanoplatelets into poly(vinyl acetate) (PVAc) through the simple solvent mixing method. TEM and XRD revealed that well exfoliated formed a continuous network throughout matrix with large amount of interconnectedness. Dynamic mechanical analysis showed inclusion significantly improves both glassy rubbery moduli matrix. Furthermore, demonstrated marked electrical conductivity up to 24.7 S m−1 thereby surprisingly rapid actuation behaviour exhibiting 100% recovery ratio in 2.5 s. Moreover, PVAc its displayed scratch self-healing capability. This work demonstrates PVAc/graphene high modulus excellent performance can be promising material many applications such as sensors fast deployable actuating devices. © 2016 Society Chemical Industry

参考文章(53)
Lin Tan, Lu Gan, Jinlian Hu, Yong Zhu, Jianping Han, Functional shape memory composite nanofibers with graphene oxide filler Composites Part A-applied Science and Manufacturing. ,vol. 76, pp. 115- 123 ,(2015) , 10.1016/J.COMPOSITESA.2015.04.015
Han-Qiao Shi, Bao-Gang Sun, Qian Liu, Zhi-Yong Yang, Kai Yi, Yi Zhang, Shao-Yun Fu, A high ductility RTM epoxy resin with relatively high modulus and Tg Journal of Polymer Research. ,vol. 22, pp. 1- 9 ,(2015) , 10.1007/S10965-015-0774-7
Jianming Guo, Zhenqing Wang, Liyong Tong, Hongqing Lv, Wenyan Liang, Shape memory and thermo-mechanical properties of shape memory polymer/carbon fiber composites Composites Part A-applied Science and Manufacturing. ,vol. 76, pp. 162- 171 ,(2015) , 10.1016/J.COMPOSITESA.2015.05.026
Hongqiu Wei, Yongtao Yao, Yanju Liu, Jinsong Leng, A dual-functional polymeric system combining shape memory with self-healing properties Composites Part B-engineering. ,vol. 83, pp. 7- 13 ,(2015) , 10.1016/J.COMPOSITESB.2015.08.019
F. H. Zhang, Z. C. Zhang, C. J. Luo, I-Ting Lin, Yanju Liu, Jinsong Leng, Stoyan K. Smoukov, Remote, fast actuation of programmable multiple shape memory composites by magnetic fields Journal of Materials Chemistry C. ,vol. 3, pp. 11290- 11293 ,(2015) , 10.1039/C5TC02464A
Dong Wang, Jing Guo, Huan Zhang, Beichen Cheng, Heng Shen, Ning Zhao, Jian Xu, Intelligent rubber with tailored properties for self-healing and shape memory Journal of Materials Chemistry. ,vol. 3, pp. 12864- 12872 ,(2015) , 10.1039/C5TA01915J
Hossein Birjandi Nejad, Jaimee M. Robertson, Patrick T. Mather, Interwoven polymer composites via dual-electrospinning with shape memory and self-healing properties MRS Communications. ,vol. 5, pp. 211- 221 ,(2015) , 10.1557/MRC.2015.39
Erika D. Rodriguez, Xiaofan Luo, Patrick T. Mather, Linear/network poly(ε-caprolactone) blends exhibiting shape memory assisted self-healing (SMASH). ACS Applied Materials & Interfaces. ,vol. 3, pp. 152- 161 ,(2011) , 10.1021/AM101012C
Cai-Li Huang, Man-Jie He, Meng Huo, Lan Du, Cong Zhan, Cheng-Jie Fan, Ke-Ke Yang, In-Joo Chin, Yu-Zhong Wang, A facile method to produce PBS-PEG/CNTs nanocomposites with controllable electro-induced shape memory effect Polymer Chemistry. ,vol. 4, pp. 3987- 3997 ,(2013) , 10.1039/C3PY00461A