Triazolinediones enable ultrafast and reversible click chemistry for the design of dynamic polymer systems
作者： Stijn Billiet , Kevin De Bruycker , Frank Driessen , Hannelore Goossens , Veronique Van Speybroeck
DOI: 10.1038/NCHEM.2023
关键词: Reversible reaction 、 Organic chemistry 、 Combinatorial chemistry 、 Click chemistry 、 Diels–Alder reaction 、 Supramolecular chemistry 、 Bioconjugation 、 Chemical reaction 、 Green chemistry 、 Chemistry 、 Reaction mechanism
摘要: With its focus on synthetic reactions that are highly specific and reliable,'click'chemistry has become a valuable tool for many scientific research areas and applications. Combining the modular, covalently bonded nature of click-chemistry linkages with an ability to reverse these linkages and reuse the constituent reactants in another click reaction, however, is a feature that is not found in most click reactions. Here we show that triazolinedione compounds can be used in click-chemistry applications. We present examples of simple and …
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