DOI: 10.1016/J.CPLETT.2010.03.092
关键词: Gibbs free energy 、 Charge density 、 Crystallography 、 Salting out 、 Accessible surface area 、 Hydrophobic effect 、 Chemistry 、 Dispersion (chemistry) 、 Particle 、 Aqueous solution 、 Chemical physics
摘要: The decrease in water accessible surface area drives the association of two large hydrophobic plates both and aqueous salt solutions: contact configuration possesses minimum Gibbs energy all cases. High charge density ions, having strong electrostatic attractions with waters, render more costly process cavity creation, as determined by classic scaled particle theory calculations, strengthen pairwise interaction. Low-charge being preferentially bound to plate surfaces due dispersion interactions, have be removed arrive at weaken