Effect of amines on the antiwear properties of P‐containing compounds as oil additives

作者: Yong Wan , Weimin Liu , Tianhui Ren , Qunji Xue

DOI: 10.1002/LS.3010060306

关键词: MoleculeX-ray photoelectron spectroscopyAmine gas treatingOrganic chemistryTertiary amineCompetitive adsorptionChemistry

摘要: This paper reports a study on the effects of concentration and molecular structure amines antiwear properties TBP, TCP TBPi, evaluated with four-ball machine. It was found that reduce P-containing additives in order primary>secondary>tertiary amine, critical amine exists at which lose their properties. XPS analysis indicated competitive adsorption onto rubbed surface causes reduction additives.

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