Towards the understanding of chloride profiles in marine exposed concrete, impact of leaching and moisture content

作者: Klaartje De Weerdt , Denisa Orsáková , Arnaud C.A. Müller , Claus K. Larsen , Bård Pedersen

DOI: 10.1016/J.CONBUILDMAT.2016.05.069

关键词: ChlorineMetallurgySeawaterMoisturePortland cementWater contentChlorideSilica fumeMaterials scienceFly ash

摘要: Abstract Cores drilled from three concrete beams submerged in sea water for 16 years at the South Western Norwegian coast were examined. The cast with different binders containing Portland cement and silica fume, fly ash or slag water-to-binder ratios (w/b) between 0.40 0.44. aim of study was to investigate whether binder composition would affect elemental changes caused by exposure thereby chloride ingress. No large differences observed. All concretes showed a 200–300 μm deep magnesium enriched zone negligible amounts sulphur chlorine surface. This followed (2–5 mm deep), which then again partially overlapped following (approximately 50 mm deep). For all concretes, moisture measurements that core not saturated, indicating self-desiccation low pore connectivity. absence considerable difference ingress investigated indicates either replacement levels are too have marked effect on chemistry, is mainly governed comparable physical properties i.e. porosity degree saturation.

参考文章(18)
Performance of Slag Concrete in Marine Environment Aci Materials Journal. ,vol. 105, pp. 628- 634 ,(2008) , 10.14359/20205
P Tourney, S Sahu, N Thaulow, E Samson, D Burke, J Marchand, PREDICTING THE MICROSTRUCTURAL DEGRADATION OF CONCRETE IN MARINE ENVIRONMENT Sixth CANMET/ACI International Conference on Durability of ConcreteCanada Centre for Mineral and Energy Technology (CANMET) of Natural Resources Canada, American Concrete Institute. ,vol. 212, pp. 1127- 1154 ,(2003) , 10.14359/12742
Ulla Hjorth Jakobsen, Karen L. Scrivener, Rachel J. Detwiler, Knut O. Kjellsen, Laura J. Powers, Wase U. Ahmed, PREPARING SPECIMENS FOR MICROSCOPY Concrete international. ,vol. 23, pp. 50- 58 ,(2001)
Tarek Uddin Mohammed, Toru Yamaji, Hidenori Hamada, Chloride diffusion, microstructure, and mineralogy of concrete after 15 years of exposure in tidal environment Aci Materials Journal. ,vol. 99, pp. 256- 263 ,(2002) , 10.14359/11971
Matthew S. Wheal, Lyndon T. Palmer, Chloride analysis of botanical samples by ICP-OES Journal of Analytical Atomic Spectrometry. ,vol. 25, pp. 1946- 1952 ,(2010) , 10.1039/C0JA00059K
K. De Weerdt, M. Ben Haha, G. Le Saout, K.O. Kjellsen, H. Justnes, B. Lothenbach, Hydration mechanisms of ternary Portland cements containing limestone powder and fly ash Cement and Concrete Research. ,vol. 41, pp. 279- 291 ,(2011) , 10.1016/J.CEMCONRES.2010.11.014
K. De Weerdt, D. Orsáková, M.R. Geiker, The impact of sulphate and magnesium on chloride binding in Portland cement paste Cement and Concrete Research. ,vol. 65, pp. 30- 40 ,(2014) , 10.1016/J.CEMCONRES.2014.07.007
Erik P Nielsen, Mette R Geiker, Chloride diffusion in partially saturated cementitious material Cement and Concrete Research. ,vol. 33, pp. 133- 138 ,(2003) , 10.1016/S0008-8846(02)00939-0