Comparison of 13C‐ and 1H‐Magnetic Resonance Spectroscopy as Techniques for the Quantitative Investigation of Dynamic Processes. The cope rearrangement in bullvalene
作者： Jean F. M. Oth , Klaus Müllen , Jean-Marie Gilles , Gerhard Schröder
关键词: Nuclear magnetic resonance spectroscopy 、 Chemistry 、 Bullvalene 、 Spectroscopy 、 Analytical chemistry 、 Fourier transform 、 Cope rearrangement 、 Molecular dynamics 、 Spins 、 Chemical physics
摘要: The potential advantages of 13C-(1H-noise decoupled) spectroscopy (in the Fourier transform mode) over 1H-spectroscopy for quantitative investigation molecular dynamic process is discussed. Cope rearrangement in bullvalene, an example complex exchange spins different magnetic sites, has been studied by both kinds as a test.
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