Synthesis, structures and oxygen atom transfer catalysis of oxo-bridged molybdenum(V) complexes with heterocyclic bidentate ligands (N,X) X=S, Se
作者： Xiaoli Ma , Carola Schulzke , Zhi Yang , Arne Ringe , Jörg Magull
DOI: 10.1016/J.POLY.2007.08.020
关键词: Stereochemistry 、 Chemistry 、 Denticity 、 Molybdenum 、 Oxygen atom 、 Catalysis 、 Crystal structure 、 Spectroscopy 、 Crystallography 、 Isostructural 、 Physical and Theoretical Chemistry 、 Inorganic chemistry 、 Materials Chemistry
摘要: The dinuclear μ-oxomolybdenum(V) complexes [Mo 2 O 3 (PyS) 4 ] ( 1 ), (PySe) ) and (4-CF -PymS) were obtained by similar reactions of the [MoO Cl (DME)] precursor with corresponding heterocyclic bidentate (N,X) ligands, X = S, Se, where PyS, PySe 4-CF -PymS are anions pyridine-2-thione, pyridine-2-selenolato 4-trifluoromethyl-2-pyrimidinthiol, respectively. All compounds characterized elemental analysis, IR, NMR, EI-MS spectroscopy X-ray diffraction. crystal structures – all include common 4+ core. Compounds isostructural. catalytic oxo-transfer properties molybdenum(V) studied use PPh in DMSO a considerably higher activity for thionato containing complex than its selenolato analogue .
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