Corona Yank in Edged Cathode Particles for Li-Ion Batteries
作者： Jagannathan Rangarajan
DOI: 10.1021/ACS.LANGMUIR.6B00336
关键词: Cathode 、 Manganese 、 Nanotechnology 、 Nickel 、 Chemical engineering 、 Corona (optical phenomenon) 、 Manganese oxide 、 Lithium 、 Ion 、 Cobalt oxide 、 Materials science
摘要: In a heuristic endeavor based on electrostatics-dynamics considerations, an attempt has been made to explain the significant enhancement (∼20%) observed in initial capacity for as-synthesized, sharp-edged cathode particles of lithium nickel manganese cobalt oxide, and oxide systems which are considered here as illustrative examples. Also, impressive retention (∼90%) milled blend these, comprising smooth surfaced with cells using respective particles, explained. Enhancement edged can be squarely attributed corona-gain process. On contrary, possible (of near-spherical particles) rationalized terms absence predominant energy drain encountered while shuttling charges across edges as-synthesized process described corona yank
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