Functional Molecular Flasks : New Properties and Reactions within Discrete, Self-Assembled Hosts
作者： Michito Yoshizawa , Jeremy K. Klosterman , Makoto Fujita
关键词: Self assembled 、 Molecule 、 Laboratory flask 、 Nanotechnology 、 Chemistry 、 Supramolecular chemistry 、 Coordination cage 、 Self-assembly 、 Supramolecular catalysis
摘要: The application of self-assembled hosts as "molecular flasks" has precipitated a surge interest in the reactivity and properties molecules within well-defined confined spaces. facile modular synthesis enabled variety differing sizes, shapes, to be prepared. This Review briefly highlights various molecular flasks synthesized before focusing on their use functional containers--specifically for encapsulation guest either engender unusual reactions or unique chemical phenomena. Such cavities now constitute new phase chemistry, which cannot achieved conventional solid, liquid, gas phases.
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