Poly(caprolactone) thin film preparation, morphology, and surface texture
作者： Darren Simon , Anthony Holland , Robert Shanks
DOI: 10.1002/APP.25228
关键词: Thin film 、 Crystallinity 、 Crystallization 、 Materials science 、 Differential scanning calorimetry 、 Surface finish 、 Composite material 、 Texture (crystalline) 、 Surface roughness 、 Spinning
摘要: The properties and surface uniformity of poly(caprolactone) (PCL) thin films were measured. Thin prepared using a spin-coating technique. Film thickness roughness correlated with variation in solution concentration, spinning speed time. Differential scanning calorimetry (DSC) was used to investigate the crystallization melting processes. enthalpy film thickness, while temperature independent thickness. In addition, found be function PCL showed progressive decrease when increased, time provided no significant influence on significantly increased concentration increased. Hot stage optical microscopy that larger spherulitic crystals present films, smaller thicker had coarser texture consistent roughness.
sci-hub.se 参考文章(24)
Jian Wang, Man Ken Cheung, Yongli Mi, Miscibility and morphology in crystalline/amorphous blends of poly(caprolactone)/poly(4-vinylphenol) as studied by DSC, FTIR, and 13 C solid state NMR Polymer. ,vol. 43, pp. 1357- 1364 ,(2002) , 10.1016/S0032-3861(01)00673-5
C.S. Ng, S.H. Teoh, T.S. Chung, D.W. Hutmacher, Simultaneous biaxial drawing of poly (ϵ-caprolactone) films Polymer. ,vol. 41, pp. 5855- 5864 ,(2000) , 10.1016/S0032-3861(99)00760-0
Daniel Keroack, Yue Zhao, Robert E. Prud'homme, Molecular orientation in crystalline miscible blends Polymer. ,vol. 40, pp. 243- 251 ,(1999) , 10.1016/S0032-3861(98)00187-6
Jörg Kressler, Chun Wang, Hans Werner Kammer, Structure Formation in Thin Poly(ε-caprolactone) Films Langmuir. ,vol. 13, pp. 4407- 4412 ,(1997) , 10.1021/LA960899R
N Chapleau, B.D Favis, P.J Carreau, Measuring the interfacial tension of polyamide/polyethylene and polycarbonate/polypropylene blends: effect of temperature Polymer. ,vol. 41, pp. 6695- 6698 ,(2000) , 10.1016/S0032-3861(00)00006-9
Jae Hyun Kim, Jyongsik Jang, Deuk-Young Lee, Wang-Cheol Zin, Thickness and Composition Dependence of the Glass Transition Temperature in Thin Homogeneous Polymer Blend Films Macromolecules. ,vol. 35, pp. 311- 313 ,(2002) , 10.1021/MA010198N
Dimitri A Ivanov, Bernard Nysten, Alain M Jonas, Atomic force microscopy imaging of single polymer spherulites during crystallization: application to a semi-crystalline blend Polymer. ,vol. 40, pp. 5899- 5905 ,(1999) , 10.1016/S0032-3861(98)00812-X
M. M. Despotopoulou, C. W. Frank, R. D. Miller, J. F. Rabolt, Kinetics of Chain Organization in Ultrathin Poly(di-n-hexylsilane) Films† Macromolecules. ,vol. 29, pp. 5797- 5804 ,(1996) , 10.1021/MA9511964
C. De Kesel, C. Lefèvre, J.B. Nagy, C. David, Blends of polycaprolactone with polyvinylalcohol: a DSC, optical microscopy and solid state NMR study Polymer. ,vol. 40, pp. 1969- 1978 ,(1999) , 10.1016/S0032-3861(98)00253-5
A. Wurm, M. Merzlyakov, C. Schick, Temperature modulated dynamic mechanical analysis Thermochimica Acta. ,vol. 330, pp. 121- 130 ,(1999) , 10.1016/S0040-6031(99)00026-X