A Ferromagnetic Salicylaldoximate/Azide MnII2MnIII6 Cluster with an S = 17 Ground State and a Single-Molecule-Magnet Response
作者： R. Vicente , M. S. El Fallah , B. Casanovas , M. Font-Bardia , A. Escuer
DOI: 10.1021/ACS.INORGCHEM.6B00662
关键词: Computational chemistry 、 Azide 、 Cluster (physics) 、 Chemistry 、 Ground state 、 Ferromagnetism 、 Crystallography 、 Coupling 、 Single-molecule magnet 、 Spin (physics)
摘要: One new MnII2MnIII6 cluster exhibiting an S = 17 spin ground state and single-molecule-magnet properties has been designed linking MnIII3-salicylaldoximate triangles tetracoordinated MnII cations by means of end-on azido bridges. The ferromagnetic coupling rationalized as a function their structural parameters.
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