A Hydrogen-Evolving Hybrid-Electrolyte Battery with Electrochemical/Photoelectrochemical Charging from Water Oxidation.
作者： Zhaoyu Jin , Panpan Li , Dan Xiao
关键词: Electrolyte 、 Oxygen evolution 、 Battery (electricity) 、 Hydrogen 、 Anode 、 Electrocatalyst 、 Electrochemistry 、 Inorganic chemistry 、 Energy storage 、 Chemistry
摘要: Decoupled hydrogen and oxygen production were successfully embedded into an aqueous dual-electrolyte (acid–base) battery for simultaneous energy storage conversion. A three-electrode configuration was adopted, involving electrocatalytic hydrogen-evolving electrode as cathode, alkaline battery-type or capacitor-type anode shuttle, a charging-assisting electro-/photoelectrochemically catalyzing water oxidation. The conceptual not only synergistically outputs electricity chemical fuels with tremendous specific power densities, but also supports various approaches to be charged by pure solar-assisted electricity.
sci-hub.se 参考文章(32)
Yu Zhao, Yu Ding, Yutao Li, Lele Peng, Hye Ryung Byon, John B. Goodenough, Guihua Yu, A chemistry and material perspective on lithium redox flow batteries towards high-density electrical energy storage Chemical Society Reviews. ,vol. 44, pp. 7968- 7996 ,(2015) , 10.1039/C5CS00289C
J. A. Turner, Sustainable Hydrogen Production Science. ,vol. 305, pp. 972- 974 ,(2004) , 10.1126/SCIENCE.1103197
Imad Moussallem, Jakob Jörissen, Ulrich Kunz, Stefan Pinnow, Thomas Turek, Chlor-alkali electrolysis with oxygen depolarized cathodes: history, present status and future prospects Journal of Applied Electrochemistry. ,vol. 38, pp. 1177- 1194 ,(2008) , 10.1007/S10800-008-9556-9
Phong D. Tran, Sing Yang Chiam, Pablo P. Boix, Yi Ren, Stevin S. Pramana, Jennifer Fize, Vincent Artero, James Barber, Novel cobalt/nickel–tungsten-sulfide catalysts for electrocatalytic hydrogen generation from water Energy and Environmental Science. ,vol. 6, pp. 2452- 2459 ,(2013) , 10.1039/C3EE40600H
Aleksandar R. Zeradjanin, Angel A. Topalov, Serhiy Cherevko, Gareth P. Keeley, Sustainable generation of hydrogen using chemicals with regional oversupply – Feasibility of the electrolysis in acido-alkaline reactor International Journal of Hydrogen Energy. ,vol. 39, pp. 16275- 16281 ,(2014) , 10.1016/J.IJHYDENE.2014.08.026
Katsuhiko Naoi, Syuichi Ishimoto, Jun-ichi Miyamoto, Wako Naoi, Second generation ‘nanohybrid supercapacitor’: Evolution of capacitive energy storage devices Energy and Environmental Science. ,vol. 5, pp. 9363- 9373 ,(2012) , 10.1039/C2EE21675B
Cheng Zhou, Yangwei Zhang, Yuanyuan Li, Jinping Liu, Construction of High-Capacitance 3D CoO@Polypyrrole Nanowire Array Electrode for Aqueous Asymmetric Supercapacitor Nano Letters. ,vol. 13, pp. 2078- 2085 ,(2013) , 10.1021/NL400378J
Nam-Soon Choi, Zonghai Chen, Stefan A. Freunberger, Xiulei Ji, Yang-Kook Sun, Khalil Amine, Gleb Yushin, Linda F. Nazar, Jaephil Cho, Peter G. Bruce, Lithiumbatterien und elektrische Doppelschichtkondensatoren: aktuelle Herausforderungen Angewandte Chemie. ,vol. 124, pp. 10134- 10166 ,(2012) , 10.1002/ANGE.201201429
P. Simon, Y. Gogotsi, B. Dunn, Where Do Batteries End and Supercapacitors Begin Science. ,vol. 343, pp. 1210- 1211 ,(2014) , 10.1126/SCIENCE.1249625
Desheng Kong, Judy J. Cha, Haotian Wang, Hye Ryoung Lee, Yi Cui, First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction Energy and Environmental Science. ,vol. 6, pp. 3553- 3558 ,(2013) , 10.1039/C3EE42413H