Intramolecular c-h amination with phosphoryl azides
作者： X. Peter Zhang , Hongjian Lu
DOI:
关键词: Intramolecular force 、 Nitrogen gas 、 Medicinal chemistry 、 Amination 、 Catalysis 、 Chemistry 、 Ring (chemistry) 、 Organic chemistry
摘要: A highly effective Co(II)-based system has been developed for catalytic intramolecular C—H amination with phosphoryl azides without the need of terminal oxidant or other additives, resulting in high-yielding production cyclophosphoramidates nitrogen gas as by-product; additional features this new include primary bonds and formation 7-membered ring structures.
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