Conductivité électrique totale de sels doubles de type iodure d'argent—polydiiodure de N pentylène N′ alkylène tétraméthyl N, N, N′, N′, diammonium
作者： G. Schmitt , J. J. Rosenberg
DOI: 10.1007/BF01006845
关键词: Electrochemistry 、 Nuclear magnetic resonance spectroscopy 、 Medicinal chemistry 、 Chemistry
摘要: Les ionenes de formule {[NMe2(CH2)5NMe2(CH2)n]2I}p (avec Me=radical methyl;n=3, 4, 5; etp le degre polymerization) ont ete prepares. Leur spectre RMN et IR est presente discute. Associes a l'iodure d'argent, ils donnent des composes conducteurs qui suivent la loi d'Arrhenius. Le systeme AgI-polydiiodure N pentylene N′ propylene tetramethyl N, N′, diammonium possede 25°C une conductivite maximale 0.01 Ω cm−1 pour composition renfermant 80% en equivalent AgI. Cette etude se place dans perspective mise au point generateurs tout solide.
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