Influence of hydrothermal reaction time on crystal qualities and photoluminescence properties of β-Ga 2 O 3 nanorods

作者: Feng Shi , Hengyang Qiao

DOI: 10.1007/S10854-020-04542-W

关键词: CrystallographyCrystallinitySingle crystalNanorodPhotoluminescenceMaterials scienceRaman spectroscopyMonoclinic crystal systemX-ray photoelectron spectroscopyHydrothermal circulation

摘要: The β-Ga2O3 nanorods were synthesized by the hydrothermal method, which characterized in detail so as to explore effects of time on their final morphologies and photoluminescence properties. X-ray diffraction pattern indicates that GaOOH precursor is completely converted into monoclinic phase. microscopic analysis shows single crystal samples are a slender shape, i.e., microrods. main element composition valence states detected photoelectron spectroscopy, whose result consistent with XRD. Raman spectrum for sample obtained at 10 h has highest intensity narrowest full width half-maximum crystallinity. spectra show emission peaks three appear blue-violet region between 375 425 nm, greatly affected time.

参考文章(38)
A. Navarro-Quezada, Z. Galazka, S. Alamé, D. Skuridina, P. Vogt, N. Esser, Surface properties of annealed semiconducting β-Ga2O3 (1 0 0) single crystals for epitaxy Applied Surface Science. ,vol. 349, pp. 368- 373 ,(2015) , 10.1016/J.APSUSC.2015.04.225
C.V. Ramana, V.V. Atuchin, I.B. Troitskaia, S.A. Gromilov, V.G. Kostrovsky, G.B. Saupe, Low-temperature synthesis of morphology controlled metastable hexagonal molybdenum trioxide (MoO3) Solid State Communications. ,vol. 149, pp. 6- 9 ,(2009) , 10.1016/J.SSC.2008.10.036
Davoud Dastan, Priyanka U. Londhe, Nandu B. Chaure, Characterization of TiO2 nanoparticles prepared using different surfactants by sol–gel method Journal of Materials Science: Materials in Electronics. ,vol. 25, pp. 3473- 3479 ,(2014) , 10.1007/S10854-014-2041-9
Victor V. Atuchin, Valery G. Kesler, Natalia V. Pervukhina, Zhaoming Zhang, Ti 2p and O 1s core levels and chemical bonding in titanium-bearing oxides Journal of Electron Spectroscopy and Related Phenomena. ,vol. 152, pp. 18- 24 ,(2006) , 10.1016/J.ELSPEC.2006.02.004
A. Cüneyt Taş, Peter J. Majewski, Fritz Aldinger, Synthesis of gallium oxide hydroxide crystals in aqueous solutions with or without urea and their calcination behavior Journal of the American Ceramic Society. ,vol. 85, pp. 1421- 1429 ,(2002) , 10.1111/J.1151-2916.2002.TB00291.X
Weirong Zhao, Yong Yang, Rui Hao, Feifei Liu, Yan Wang, Min Tan, Jing Tang, Daqing Ren, Dongye Zhao, Synthesis of mesoporous β-Ga2O3 nanorods using PEG as template: Preparation, characterization and photocatalytic properties Journal of Hazardous Materials. ,vol. 192, pp. 1548- 1554 ,(2011) , 10.1016/J.JHAZMAT.2011.06.073
Jun Zhang, Feihong Jiang, Catalytic growth of Ga2O3 nanowires by physical evaporation and their photoluminescence properties principles and practice of constraint programming. ,vol. 289, pp. 243- 249 ,(2003) , 10.1016/S0301-0104(03)00045-4
N.N. Golovnev, M.S. Molokeev, S.N. Vereshchagin, V.V. Atuchin, Calcium and strontium thiobarbiturates with discrete and polymeric structures Journal of Coordination Chemistry. ,vol. 66, pp. 4119- 4130 ,(2013) , 10.1080/00958972.2013.860450
Stjepko Krehula, Mira Ristić, Shiro Kubuki, Yusuke Iida, Martin Fabián, Svetozar Musić, The formation and microstructural properties of uniform α-GaOOH particles and their calcination products Journal of Alloys and Compounds. ,vol. 620, pp. 217- 227 ,(2015) , 10.1016/J.JALLCOM.2014.09.134
Ivanka T. Savatinova, Mariana K. Kuneva, Zelma Levi, Victor V. Atuchin, C. C. Ziling, Mario N. Armenise, Proton exchange in LiTaO3 with different stoichiometric composition Integrated Optics and Optoelectronics II. ,vol. 1374, pp. 37- 46 ,(1991) , 10.1117/12.24953