Chemistry Surrounding Group 7 Complexes that Possess Poly(pyrazolyl)borate Ligands
作者： Marty Lail , Karl A. Pittard , T. Brent Gunnoe
DOI: 10.1016/S0065-3055(07)56002-8
关键词: Hydroamination 、 Redox 、 Metathesis 、 Rhenium 、 Catalysis 、 Transition metal 、 Chemistry 、 Oxidation state 、 Organic chemistry 、 Polymer chemistry 、 Reactivity (chemistry)
摘要: Publisher Summary This chapter reviews the chemistry observed with Group 7 (Mn, Tc, and Re) poly(pyrazolyl)borate complexes. The redox flexibility of these transition metals variability poly(pyrazolyl) borate ligands have resulted in a wide range chemistry. Poly(pyrazolyl)borate support numerous complexes involving metals. has allowed access to oxidation states geometries as well provided Mn, Re diversity reactivity. As result attractive features, complexes, including coordination all elements groups 1 through 13 some lanthanides actinides. Transition metal containing imido are interest due their possible role olefin aziridinations, metal-mediated metathesis multiple bonds, ammoxidation reactions, C–H activation sequences catalytic hydroamination C–C bonds. In addition, discusses about Rhenium, Manganese, Technetium respect high low state
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