Development of binaphthyl-based chiral dienes for rhodium(I)-catalyzed asymmetric arylation of N,N-dimethylsulfamoyl-protected aldimines.
作者： Ziping Cao , Haifeng Du
DOI: 10.1021/OL1008087
关键词: Organic chemistry 、 Chemistry 、 Catalysis 、 Rhodium 、 Enantioselective synthesis 、 Aldimine
摘要: A variety of binaphthyl-based chiral dienes were synthesized and utilized as steering ligands for the enantioselective arylation N,N-dimethylsulfamoyl-protected aldimines with arylboronic acids, moderate to good yields up 84% ee achieved.
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