Trispyrazolylborate Complexes: An Advanced Synthesis Experiment Using Paramagnetic NMR, Variable-Temperature NMR, and EPR Spectroscopies
作者： Timothy N. Abell , Robert M. McCarrick , Stacey Lowery Bretz , David L. Tierney
DOI: 10.1021/ACS.JCHEMED.7B00302
关键词: Coordination complex 、 Chemistry 、 Trispyrazolylborate 、 Infrared spectroscopy 、 Nuclear magnetic resonance 、 Nuclear magnetic resonance spectroscopy 、 Electron paramagnetic resonance 、 Electronic structure 、 Paramagnetism 、 Physical chemistry 、 Transition metal
摘要: A structured inquiry experiment for inorganic synthesis has been developed to introduce undergraduate students advanced spectroscopic techniques including paramagnetic nuclear magnetic resonance and electron resonance. Students synthesize multiple complexes with unknown first row transition metals identify the by correlating data electronic structure. are assessed through an oral presentation of their spectral analyses conclusions. Data included in Supporting Information institutions without access EPR.
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