Photoelectron spectra and ionic structure of carbon dioxide, carbon disulphide and sulphur dioxide

摘要: Abstract Photoelectron spectra of carbon dioxide, disulphide and sulphur dioxide excited by 584 A radiation have been measured at a resolution 20 mV over the whole energy range. Ionization potentials, vibration frequencies ions relative vibrational transition probabilities are presented for used to derived structural information about ionic states. analysis photoelectron spectrum leads estimates geometry in different states conclusion that dπ bonding is effective one 4b2 or 1a2 orbitals.