Self-assembly of CNH nanocages with remarkable catalytic performance
作者： Jing Zhang , Zhijian Wang , Li Li , Jianghong Zhao , Jianfeng Zheng
DOI: 10.1039/C4TA00765D
关键词: Chemical engineering 、 Inorganic chemistry 、 Nanocages 、 Catalysis 、 Self-assembly 、 Hydrogen peroxide 、 Electrochemistry 、 Adsorption 、 Melamine 、 Cyanuric chloride 、 Chemistry
摘要: Melamine and cyanuric chloride self-assemble into CNH nanocages. The nanocages have uniform mesosized cages with micropores in the walls, which is beneficial to diffusion adsorption of O2, as well rapid electrochemical catalysis O2 hydrogen peroxide. Moreover, theoretical calculations confirm that triangle-shaped are only sites catalyzed center micropores.
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sci-hub.se 参考文章(27)
Heejin Kim, Kirak Lee, Seong Ihl Woo, Yousung Jung, On the mechanism of enhanced oxygen reduction reaction in nitrogen-doped graphene nanoribbons Physical Chemistry Chemical Physics. ,vol. 13, pp. 17505- 17510 ,(2011) , 10.1039/C1CP21665A
Ruili Liu, Dongqing Wu, Xinliang Feng, Klaus Müllen, Nitrogen‐Doped Ordered Mesoporous Graphitic Arrays with High Electrocatalytic Activity for Oxygen Reduction Angewandte Chemie. ,vol. 49, pp. 2565- 2569 ,(2010) , 10.1002/ANIE.200907289
Lipeng Zhang, Zhenhai Xia, Mechanisms of Oxygen Reduction Reaction on Nitrogen-Doped Graphene for Fuel Cells Journal of Physical Chemistry C. ,vol. 115, pp. 11170- 11176 ,(2011) , 10.1021/JP201991J
Iwao Tabushi, Cyclodextrin catalysis as a model for enzyme action Accounts of Chemical Research. ,vol. 15, pp. 66- 72 ,(1982) , 10.1021/AR00075A001
Richard Wolfenden, Mark J. Snider, The Depth of Chemical Time and the Power of Enzymes as Catalysts Accounts of Chemical Research. ,vol. 34, pp. 938- 945 ,(2001) , 10.1021/AR000058I
K. Gong, F. Du, Z. Xia, M. Durstock, L. Dai, Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction. Science. ,vol. 323, pp. 760- 764 ,(2009) , 10.1126/SCIENCE.1168049
Melissa L. Merlau, Maria del Pilar Mejia, SonBinh T. Nguyen, Joseph T. Hupp, Artificial Enzymes Formed through Directed Assembly of Molecular Square Encapsulated Epoxidation Catalysts Angewandte Chemie International Edition. ,vol. 40, pp. 4239- 4242 ,(2001) , 10.1002/1521-3773(20011119)40:22<4239::AID-ANIE4239>3.0.CO;2-E
E. Riedo, F. Comin, J. Chevrier, A. M. Bonnot, Composition and chemical bonding of pulsed laser deposited carbon nitride thin films Journal of Applied Physics. ,vol. 88, pp. 4365- 4370 ,(2000) , 10.1063/1.1309041
V Braun, Active transport of iron and siderophore antibiotics. Current Opinion in Microbiology. ,vol. 5, pp. 194- 201 ,(2002) , 10.1016/S1369-5274(02)00298-9
Takashi Ikeda, Mauro Boero, Sheng-Feng Huang, Kiyoyuki Terakura, Masaharu Oshima, Jun-ichi Ozaki, Carbon Alloy Catalysts: Active Sites for Oxygen Reduction Reaction Journal of Physical Chemistry C. ,vol. 112, pp. 14706- 14709 ,(2008) , 10.1021/JP806084D