Nitroalkanes in C-C bond forming reactions : a crystal structure of a complex of a guanidine catalyst and a nitroalkane substrate
作者： Eddie van Aken , Hans Wynberg , Fré van Bolhuis , Joël Jaud , Jean Claude Négrel
DOI: 10.3891/ACTA.CHEM.SCAND.47-0122
关键词: Nitro compound 、 Catalysis 、 Substrate (chemistry) 、 Bicyclic molecule 、 Guanidine 、 Crystal structure 、 Chemistry 、 Organic chemistry 、 Molecule 、 Polymer chemistry 、 Nitroalkane
摘要: 1,5,7-Triazabicyclo[4.4.0]dec-5-ene, a good catalyst for nitroalkanes in C-C bond forming reactions, forms 1:1 complex with phenylnitromethane as substrate. The mode of complexation between the and substrate is shown by crystal structure 3
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