Advanced supercritical Methyl acetate method for biodiesel production from Pongamia pinnata oil
作者： Fadjar Goembira , Shiro Saka
DOI: 10.1016/J.RENENE.2015.06.022
关键词: Transesterification 、 Methyl acetate 、 Pulp and paper industry 、 Biodiesel production 、 Organic chemistry 、 Pongamia 、 Acetic acid 、 Triacetin 、 Fatty acid methyl ester 、 Chemistry 、 Biodiesel
摘要: Abstract At present, alkali-catalyzed transesterification process is widely used in biodiesel production. However, this up to 88% of total production cost for the feedstock, due requirement using low free fatty acid (FFA) content feedstocks that are commonly attributed refined edible plant-oils. This work was, therefore, carried out know potential use non-edible Pongamia pinnata oil Instead a transesterification, applied an interesterification called one-step supercritical methyl acetate method under reaction condition 300 °C/20 MPa/45 min/42 M ratio oil. In glycerol-free method, 10wt% aqueous acetic was added as additive proceed such condition. It found high FFA did not give any adverse effect on highest yield 96.6wt% FAME and 11.5wt% triacetin (total 108.1wt%) achievable. Both products were miscible their evaluation properties showed compliance towards standards.
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Fadjar Goembira, Shiro Saka, Factors Affecting Biodiesel Yield in Interesterification of Rapeseed Oil by Supercritical Methyl Acetate Zero-Carbon Energy Kyoto 2011. pp. 147- 152 ,(2012) , 10.1007/978-4-431-54067-0_16
Jiayu Xin, Hiroaki Imahara, Shiro Saka, Kinetics on the oxidation of biodiesel stabilized with antioxidant Fuel. ,vol. 88, pp. 282- 286 ,(2009) , 10.1016/J.FUEL.2008.08.018
Hiroaki Imahara, Eiji Minami, Shusaku Hari, Shiro Saka, Thermal stability of biodiesel in supercritical methanol Fuel. ,vol. 87, pp. 1- 6 ,(2008) , 10.1016/J.FUEL.2007.04.003
Sanjib Kumar Karmee, Anju Chadha, Preparation of biodiesel from crude oil of Pongamia pinnata. Bioresource Technology. ,vol. 96, pp. 1425- 1429 ,(2005) , 10.1016/J.BIORTECH.2004.12.011
B. K. De, D. K. Bhattacharyya, Biodiesel from minor vegetable oils like karanja oil and nahor oil Fett-lipid. ,vol. 101, pp. 404- 406 ,(1999) , 10.1002/(SICI)1521-4133(199910)101:10<404::AID-LIPI404>3.0.CO;2-K
Lin Lin, Zhou Cunshan, Saritporn Vittayapadung, Shen Xiangqian, Dong Mingdong, Opportunities and challenges for biodiesel fuel Applied Energy. ,vol. 88, pp. 1020- 1031 ,(2011) , 10.1016/J.APENERGY.2010.09.029
Y.C. Sharma, B. Singh, Development of biodiesel from karanja, a tree found in rural India Fuel. ,vol. 87, pp. 1740- 1742 ,(2008) , 10.1016/J.FUEL.2007.08.001
Juan A Melero, Rafael van Grieken, Gabriel Morales, Marta Paniagua, None, Acidic Mesoporous Silica for the Acetylation of Glycerol: Synthesis of Bioadditives to Petrol Fuel Energy & Fuels. ,vol. 21, pp. 1782- 1791 ,(2007) , 10.1021/EF060647Q
Zan Win Moh Moh Phoo, Luis F Razon, Gerhard Knothe, Zul Ilham, Fadjar Goembira, Cynthia F Madrazo, Susan A Roces, Shiro Saka, None, Evaluation of Indian milkweed (Calotropis gigantea) seed oil as alternative feedstock for biodiesel Industrial Crops and Products. ,vol. 54, pp. 226- 232 ,(2014) , 10.1016/J.INDCROP.2014.01.029
Fadjar Goembira, Kosuke Matsuura, Shiro Saka, Biodiesel production from rapeseed oil by various supercritical carboxylate esters Fuel. ,vol. 97, pp. 373- 378 ,(2012) , 10.1016/J.FUEL.2012.02.051