A one-dimensional Mn(II)-based metal organic oxide: structure and properties
作者： Fa-Nian Shi , Yi-Wen Bai , Miao Lu , C. Cruz , M. S. Reis
DOI: 10.1007/S11243-017-0165-5
关键词: Crystallography 、 Inorganic chemistry 、 Oxide 、 Metal 、 Decomposition 、 Organometallic chemistry 、 Catalysis 、 Antiferromagnetism 、 Ferromagnetism 、 Organic Oxide 、 Chemistry
摘要: A one-dimensional metal organic oxide of Mn(II), with formula [Mn3(OH)2(Hpdc)2]n (H3pdc = 3,5-pyrazoledicarboxylic acid), was prepared via the hydrothermal method and its structure solved by single-crystal X-ray diffraction. The compound exhibits a three-dimensional framework structure, comprising three crystallographically unique Mn atoms bridged OH ligands (O9 O10) O from Hpdc ligands, forming metal–organic chains. Two kinds magnetic exchange are observed: strong antiferromagnetic intra-chain interaction, arising short distance between Mn(II) centers, ferromagnetic inter-chain due to larger distances shows good photocatalytic activity for decomposition methylene blue in aqueous medium under simulated sunlight.
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