A study of the electronic and physical properties of SnO2 thin films as a function of substrate temperature

作者: O. Erken , O.M. Ozkendir , M. Gunes , E. Harputlu , C. Ulutas

DOI: 10.1016/J.CERAMINT.2019.06.153

关键词: Thin filmCrystal structureX-ray absorption fine structureTetragonal crystal systemMaterials scienceAbsorption spectroscopyExtended X-ray absorption fine structureX-ray absorption spectroscopyTin dioxideAnalytical chemistry

摘要: Abstract In this work, tin dioxide (SnO2) thin films were prepared at various substrate temperatures (380–440 °C, in steps of 20 °C) on glass substrates by the Spray Pyrolysis Method. X-ray Diffraction (XRD) measurements revealed that SnO2 formed a tetragonal crystallized structure. The electronic structure several investigated with collected Absorption Spectroscopy (XAS) data. crystal analysis was also supported Extended Fine Structure (EXAFS) data extracted from (XAFS) Unstable behaviors detected samples due to metastable SnO formations as result phase transitions during annealing processes. Clear information atomic displacements picture mechanism obtained EXAFS found exhibit high transmittance (average 90%) 400–1100 nm interval. thickness film (t) and refractive index (n) calculated spectra visible region using envelope method. direct energy band gaps 4.01–4.09 eV. Atomic force microscope (AFM) performed order investigate surface roughness films.

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