Black reduced porous SnO2 nanosheets for CO2 electroreduction with high formate selectivity and low overpotential
作者： Guangbo Liu , Zhonghua Li , Jianjian Shi , Kun Sun , Yujin Ji
DOI: 10.1016/J.APCATB.2019.118134
关键词: Overpotential 、 Vacancy defect 、 Electrocatalyst 、 Reversible hydrogen electrode 、 Inorganic chemistry 、 Conductivity 、 Density functional theory 、 Formate 、 Materials science 、 Faraday efficiency
摘要: The great bottleneck that lies in CO 2 reduction reaction (CO 2 RR) electrocatalysts is to simultaneously enhance their conductivity and density of active sites. Herein, we developed a black reduced porous SnO 2 nanosheets electrocatalyst that enabled possessing both metallic conductivity and high density of active sites via vacancy engineering. The black reduced porous SnO 2 nanosheets showed high activity and selectivity for CO 2 RR to formate, with maximum Faradaic efficiency (FE) of 92.4% at the low overpotential of 0.51 V …
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