Absorption and mid-infrared emission spectroscopy of Dy3+ in Ge-As(or Ga)-S glasses
作者： Jong Heo , Yong Beom Shin
DOI: 10.1016/0022-3093(95)00579-X
关键词: Relaxation (NMR) 、 Infrared spectroscopy 、 Absorption (electromagnetic radiation) 、 Laser 、 Doping 、 Chemistry 、 Analytical chemistry 、 Absorption spectroscopy 、 Emission spectrum 、 Inorganic chemistry 、 Infrared
摘要: Abstract Ge-As-S and Ge-Ga-S glasses doped with Dy 3+ were prepared the emission characteristics of four infrared fluorescent emissions at 1.33, 1.75, 2.90 4.38 μm evaluated. High oscillator strengths large intensity parameters originate from highly covalent nature bonds in glasses. Measured lifetimes glass are 728 4550 μs for 6 H 11/2 → 15/2 (1.75 μm) 13/2 (2.90 transitions, respectively. Quantum efficiencies 32.8 87.2% above transitions compare well values reported previously. Multiphonon relaxation rates are4 orders magnitude less than those silicate glasses, which provide good opportunities future laser applications.
harvard.edu
postech.ac.kr
elsevier.com参考文章(14)
L. Wetenkamp, G.F. West, H. Többen, Optical properties of rare earth-doped ZBLAN glasses Journal of Non-crystalline Solids. ,vol. 140, pp. 35- 40 ,(1992) , 10.1016/S0022-3093(05)80737-9
R. Reisfeld, J. Hormadaly, A. Muranevich, Intensity parameters, radiative transitions and non-radiative relaxations of Ho3+ in various tellurite glasses☆ Chemical Physics Letters. ,vol. 38, pp. 188- 191 ,(1976) , 10.1016/0009-2614(76)80287-4
Yong Beom Shin, Joo Nyung Jang, Jong Heo, Mid-infrared light emission characteristics of Ho3+-doped chalcogenide and heavy-metal oxide glasses Optical and Quantum Electronics. ,vol. 27, pp. 379- 386 ,(1995) , 10.1007/BF00563573
R. Reisfeld, J. Hormadaly, A. Muranevich, Absorption and emission of Ho3+ in germanate glasses Journal of Non-crystalline Solids. ,vol. 29, pp. 323- 332 ,(1978) , 10.1016/0022-3093(78)90153-9
K. Wei, D. P. Machewirth, J. Wenzel, E. Snitzer, G. H. Sigel, Spectroscopy of Dy 3+ in Ge–Ga–S glass and its suitability for 1.3-μm fiber-optical amplifier applications Optics Letters. ,vol. 19, pp. 904- 906 ,(1994) , 10.1364/OL.19.000904
R. Reisfeld, M. Eyal, E. Greenberg, C.K. Jørgensen, Luminescence of six J-levels of holmium(III) in barium zirconium fluoride glass at room temperature Chemical Physics Letters. ,vol. 118, pp. 25- 28 ,(1985) , 10.1016/0009-2614(85)85258-1
Jon Heo, Yong Beom Shin, Joo Nyung Jang, Spectroscopic analysis of Tm(3+) in PbO-Bi(2)O(3)-Ga(2)O(3) glass. Applied Optics. ,vol. 34, pp. 4284- 4289 ,(1995) , 10.1364/AO.34.004284
J Hormadaly, R Reisfeld, Intensity parameters and laser analysis of Pr3+ and Dy3+ in oxide glasses☆ Journal of Non-crystalline Solids. ,vol. 30, pp. 337- 348 ,(1979) , 10.1016/0022-3093(79)90171-6
G. S. Ofelt, Intensities of Crystal Spectra of Rare‐Earth Ions Journal of Chemical Physics. ,vol. 37, pp. 511- 520 ,(1962) , 10.1063/1.1701366
K. Wei, D.P. Machewirth, J. Wenzel, E. Snitzer, G.H. Sigel, Pr3+-doped GeGaS glasses for 1.3 μm optical fiber amplifiers Journal of Non-Crystalline Solids. ,vol. 182, pp. 257- 261 ,(1995) , 10.1016/0022-3093(94)00513-3