α-Amino acid-promoted asymmetric allylation of aldehydes with allylstannanes
作者： Akira Yanagisawa , Yoko Nakamura , Takayoshi Arai
DOI: 10.1016/J.TETASY.2004.04.036
关键词: Aspartic acid 、 Chemistry 、 Organic chemistry 、 Amino acid 、 Optically active
摘要: Abstract An asymmetric allylation of aldehydes with tetraallyltin and other allylstannanes was achieved using l -aspartic acid as a chiral promoter in DMF. Various optically active homoallylic alcohols were obtained high yields moderate enantioselectivities up to 40% ee.
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