Room Temperature Magnetic Switchability Assisted by Hysteretic Valence Tautomerism in a Layered Two-Dimensional Manganese-Radical Coordination Framework.

作者: Anthony Lannes , Yan Suffren , Jean Bernard Tommasino , Rodica Chiriac , François Toche

DOI: 10.1021/JACS.6B10544

关键词: ChemistryCrystallographyValence (chemistry)Coordination polymerMagnetic susceptibilityX-ray absorption spectroscopyAnalytical chemistryCrystal structureElectron paramagnetic resonanceDiamagnetismManganese

摘要: … bond lengths while the third one (namely, B) displays classical N—O • bonds over the temperature … not, as short and long bonds are found on a same “NITIm” moiety and the N—O mean …

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