The assessment of miscibility and morphology of poly(ε-caprolactone) and poly(para-chlorostyrene) blends
作者： Ayse Z Aroguz , Hasan H Engin , Bahattin M Baysal , None
DOI: 10.1016/J.EURPOLYMJ.2006.11.010
关键词: Flory–Huggins solution theory 、 Miscibility 、 Thermal analysis 、 Materials science 、 Analytical chemistry 、 Polymer blend 、 Caprolactone 、 Glass transition 、 Melting-point depression 、 Polymer chemistry 、 Differential scanning calorimetry 、 Organic chemistry 、 General Physics and Astronomy 、 Polymers and Plastics
摘要: Abstract The miscibility and morphology of poly( e -caprolactone) (PCl) poly(para-chlorostyrene) (PpClS) blend were investigated by using thermal analysis, morphological viscometry, the study melting point depression. A single glass transition temperature was observed differential scanning calorimetry (DSC) for PCl/PpClS blends in whole compositional range (0/100, 25/75, 50/50, 62.5/37.5, 75/25, 90/10). Morphology polymers their studied electron microscopy (SEM). Fourier transform infrared spectra samples obtained spectrometer. Up to 12 cm −1 shifts carbonyl stretching band PCl detected PpClS rich blends. viscosity PCl, has also been investigate according criteria Δ b , Δ[ η ]. Using this data, interaction parameters α μ based on Chee Sun et al. approaches determined. These indicated that is miscible all proportions up 90% content depression examined obtain parameter, χ 12 system. found be composition dependent. Negative values parameter support system blend.
elsevier.com
sci-hub.se 参考文章(28)
Pierre Sarazin, Basil D. Favis, Influence of temperature-induced coalescence effects on co-continuous morphology in poly(ε-caprolactone)/polystyrene blends Polymer. ,vol. 46, pp. 5966- 5978 ,(2005) , 10.1016/J.POLYMER.2005.04.064
K.K. Chee, Determination of polymer-polymer miscibility by viscometry European Polymer Journal. ,vol. 26, pp. 423- 426 ,(1990) , 10.1016/0014-3057(90)90044-5
F. C. Bragança, D. S. Rosa, Thermal, mechanical and morphological analysis of poly(ε-caprolactone), cellulose acetate and their blends Polymers for Advanced Technologies. ,vol. 14, pp. 669- 675 ,(2003) , 10.1002/PAT.381
B AMEDURI, R PRUDHOMME, Miscibility behaviour of ternary poly(caprolactone)/poly(vinyl chloride)/chlorinated poly(vinyl chloride) blends Polymer. ,vol. 29, pp. 1052- 1057 ,(1988) , 10.1016/0032-3861(88)90014-6
A.Z. Aroguz, B.M. Baysal, Miscibility studies on blends of poly(phenylene oxide)/brominated polystyrene by viscometry European Polymer Journal. ,vol. 42, pp. 311- 315 ,(2006) , 10.1016/J.EURPOLYMJ.2005.07.012
ZHU PINGPING, A NEW CRITERION OF POLYMER-POLYMER MISCIBILITY DETECTED BY VISCOMETRY European Polymer Journal. ,vol. 33, pp. 411- 413 ,(1997) , 10.1016/S0014-3057(96)00151-6
Zhenhua Sun, Wei Wang, Zhiliu Feng, CRITERION OF POLYMER POLYMER MISCIBILITY DETERMINED BY VISCOMETRY European Polymer Journal. ,vol. 28, pp. 1259- 1261 ,(1992) , 10.1016/0014-3057(92)90215-N
Bahattin Baysal, W.H. Stockmayer, Terminal-mode dielectric relaxation in the ternary system poly(ε-caprolactone)/poly(4-chlorostyrene) /dioxane Journal of Molecular Liquids. ,vol. 56, pp. 175- 181 ,(1993) , 10.1016/0167-7322(93)80025-Q
H.M Shabana, R.H Olley, D.C Bassett, B.-J Jungnickel, Phase separation induced by crystallization in blends of polycaprolactone and polystyrene: an investigation by etching and electron microscopy Polymer. ,vol. 41, pp. 5513- 5523 ,(2000) , 10.1016/S0032-3861(99)00713-2
R.K. Wanchoo, P.K. Sharma, Viscometric study on the compatibility of some water-soluble polymer–polymer mixtures European Polymer Journal. ,vol. 39, pp. 1481- 1490 ,(2003) , 10.1016/S0014-3057(02)00386-5