Catalytic determination of iodine in serum at nanogram levels using the As(III)/Ce(IV) reaction

作者: P. J. Ke , R. J. Thibert , R. J. Walton , D. K. Soules

DOI: 10.1007/BF01218002

关键词: IodideCeriumIodineChemistryCatalysisSpectrophotometryReaction rateInorganic chemistryArsenicNuclear chemistryChemical reaction

摘要: A catalytic determination of iodine using the As(III)/Ce(IV) reaction has been developed. The difference in rate due to catalysis by iodide was measured spectrophotometrically at 310 nm. Optimum conditions were investigated order obtain a greater sensitivity iodine. method can be satisfactorily used for samples containing 0.4 10.0 ng range, with an overall error less than 6 %. serum, and gives results which compare favorably present clinical chemistry procedure.

参考文章(26)
Norbert W. Tietz, Fundamentals of Clinical Chemistry ,(1970)
Louise W Faulkner, Richard P Levy, Jack R Leonards, Simplified technic for the determination of serum protein-bound iodine. Clinical Chemistry. ,vol. 7, pp. 637- 645 ,(1961) , 10.1093/CLINCHEM/7.6.637
Olav Per Foss, Lawrence V. Hankes, D.D. Van Slyke, A study of the alkaline ashing method for determination of protein-bound iodine in serum. Clinica Chimica Acta. ,vol. 5, pp. 301- 326 ,(1960) , 10.1016/0009-8981(60)90135-2
H. V. Malmstadt, T. P. Hadjiioannou, ULTRAMICRODETERMINATION OF IODINE BY A RAPID AUTOMATIC REACTION-RATE METHOD Analytical Chemistry. ,vol. 35, pp. 2157- 2161 ,(1963) , 10.1021/AC60206A050
Viktor Štolc, Interference of certain ions with the catalytic action of iodine in the Sandell-Kolthoff reaction Fresenius' Zeitschrift für Analytische Chemie. ,vol. 183, pp. 262- 267 ,(1961) , 10.1007/BF00474698
Pedro A. Rodriguez, Harry L. Pardue, Kinetics of the iodide-catalyzed reaction between cerium(IV) and arsenic(III) in sulfuric acid medium Analytical Chemistry. ,vol. 39, pp. 1369- 1376 ,(1967) , 10.1021/AC60280A004
J. J. Custer, Samuel Natelson, Spectrophotometric Determination of Microquantities of Iodine Analytical Chemistry. ,vol. 21, pp. 1005- 1009 ,(1949) , 10.1021/AC60032A040
Allen Lein, Neena Schwartz, Ceric Sulfate-Arsenious Acid Reaction in Microdetermination of Iodine Analytical Chemistry. ,vol. 23, pp. 1507- 1510 ,(1951) , 10.1021/AC60058A049
Albert L. Chaney, Improvements in determination of iodine in blood Industrial & Engineering Chemistry Analytical Edition. ,vol. 12, pp. 179- 181 ,(1940) , 10.1021/AC50143A030