Ternary MEH-PPV-CuInS2/ZnO solar cells with tunable CuInS2 content
作者： Wenjin Yue , Mingtai Wang , Guangjun Nie
DOI: 10.1016/J.SOLENER.2013.10.040
关键词: Optoelectronics 、 Materials science 、 Quantum dot 、 Ternary operation 、 Nanorod 、 Effective nuclear charge 、 Nanocrystal 、 Energy conversion efficiency 、 Electron acceptor 、 Photovoltaic system
摘要: Abstract The paper reports novel ternary MEH-PPV-CuInS2/ZnO solar cells fabricated by incorporating CuInS2 quantum dots (QDs) into pristine MEH-PPV as light-harvester and vertically aligned ZnO nanorod array electron acceptor. Results show that, exhibit increased photovoltaic performance compared to MEH-PPV/ZnO devices the dependent on weight ratio (R) between MEH-PPV, resulting in a peak power conversion efficiency of 2.48% for R = 0.6 at 15.85 mW/cm2 monochromatic illumination. It is revealed that Jsc due improved light-harvesting, additional MEH-PPV/CuInS2 interfaces exciton dissociation, formation channels effective charge transport, while Voc decreased recombination are attributed modification surface QDs which reduces defect concentration ZnO. However, Jsc, too high R value serious aggregations inorganic nanocrystals not well dispersed organic matrix.
harvard.edu
cheric.org
elsevier.com参考文章(57)
Qifeng Zhang, Supan Yodyingyong, Junting Xi, Daniel Myers, Guozhong Cao, Oxide nanowires for solar cell applications Nanoscale. ,vol. 4, pp. 1436- 1445 ,(2012) , 10.1039/C2NR11595F
Peng Wang, Liduo Wang, Beibei Ma, Bin Li, Yong Qiu, TiO2 surface modification and characterization with nanosized PbS in dye-sensitized solar cells. Journal of Physical Chemistry B. ,vol. 110, pp. 14406- 14409 ,(2006) , 10.1021/JP060390X
Mohammad Afzaal, Paul O'Brien, Recent developments in II–VI and III–VI semiconductors and their applications in solar cells Journal of Materials Chemistry. ,vol. 16, pp. 1597- 1602 ,(2006) , 10.1039/B512182E
Lori E. Greene, Matt Law, Joshua Goldberger, Franklin Kim, Justin C. Johnson, Yanfeng Zhang, Richard J. Saykally, Peidong Yang, Low-temperature wafer-scale production of ZnO nanowire arrays. Angewandte Chemie. ,vol. 42, pp. 3031- 3034 ,(2003) , 10.1002/ANIE.200351461
Brian R. Saunders, Michael L. Turner, Nanoparticle–polymer photovoltaic cells Advances in Colloid and Interface Science. ,vol. 138, pp. 1- 23 ,(2008) , 10.1016/J.CIS.2007.09.001
Jiamin Feng, Jianjun Han, Xiujian Zhao, Synthesis of CuInS2 quantum dots on TiO2 porous films by solvothermal method for absorption layer of solar cells Progress in Organic Coatings. ,vol. 64, pp. 268- 273 ,(2009) , 10.1016/J.PORGCOAT.2008.08.022
Jayesh D. Patel, Tapas K. Chaudhuri, Synthesis of PbS/poly (vinyl-pyrrolidone) nanocomposite Materials Research Bulletin. ,vol. 44, pp. 1647- 1651 ,(2009) , 10.1016/J.MATERRESBULL.2009.04.010
Kazuko Takanezawa, Kouske Hirota, Qing-Shuo Wei, Keisuke Tajima, Kazuhito Hashimoto, Efficient Charge Collection with ZnO Nanorod Array in Hybrid Photovoltaic Devices Journal of Physical Chemistry C. ,vol. 111, pp. 7218- 7223 ,(2007) , 10.1021/JP071418N
H.J. Lewerenz, Development of copperindiumdisulfide into a solar material Solar Energy Materials and Solar Cells. ,vol. 83, pp. 395- 407 ,(2004) , 10.1016/J.SOLMAT.2004.02.034
Rakchart Traiphol, Nipaphat Charoenthai, Toemsak Srikhirin, Teerakiat Kerdcharoen, Tanakorn Osotchan, Thitima Maturos, Chain organization and photophysics of conjugated polymer in poor solvents: Aggregates, agglomerates and collapsed coils Polymer. ,vol. 48, pp. 813- 826 ,(2007) , 10.1016/J.POLYMER.2006.12.003