Carbon nanotubes-CuO/SnO2 based gas sensor for detecting H2S in low concentration.

作者: Jun Fan , Ping Liu , Xiaohong Chen , Honglei Zhou , Shaoli Fu

DOI: 10.1088/1361-6528/AB3CB3

关键词: Carbon nanotubeNanomaterialsDopingSelectivityNanofiberAnnealing (metallurgy)Composite numberChemical engineeringMaterials scienceElectrospinning

摘要: Porous CuO/SnO2 nanofibers were prepared by co-dissolution and electrospinning, followed annealing, compounded with different amounts of carbon nanotubes (CNTs, 0-5 wt%). The performance the composite based sensor was tested in concentrations H2S range from 0.1 to 0.5 ppm. results showed that gas doped CNTs (CNTs-CuO/SnO2) has a low optimum operating temperature, 40 °C, good behavior detecting concentration H2S, short response recovery time (8.3 11.5 s, respectively). And at same time, compared other gases, 3 wt% CNTs-CuO/SnO2 nanomaterial had excellent selectivity concentrations. great advantages H2S.

参考文章(21)
Yan Zhao, Xiuli He, Jianping Li, Xiaoguang Gao, Jian Jia, Porous CuO/SnO2 composite nanofibers fabricated by electrospinning and their H2S sensing properties Sensors and Actuators B-chemical. ,vol. 165, pp. 82- 87 ,(2012) , 10.1016/J.SNB.2012.02.020
Chatchawal Wongchoosuk, Anurat Wisitsoraat, Ditsayut Phokharatkul, Adisorn Tuantranont, Teerakiat Kerdcharoen, Multi-walled carbon nanotube-doped tungsten oxide thin films for hydrogen gas sensing. Sensors. ,vol. 10, pp. 7705- 7715 ,(2010) , 10.3390/S100807705
Kwon-Il Choi, Hyo-Joong Kim, Yun Chan Kang, Jong-Heun Lee, Ultraselective and ultrasensitive detection of H2S in highly humid atmosphere using CuO-loaded SnO2 hollow spheres for real-time diagnosis of halitosis Sensors and Actuators B-chemical. ,vol. 194, pp. 371- 376 ,(2014) , 10.1016/J.SNB.2013.12.111
A Tangerman, E G Winkel, Extra-oral halitosis: an overview Journal of Breath Research. ,vol. 4, pp. 017003- ,(2010) , 10.1088/1752-7155/4/1/017003
Minqiang Li, Jinhuai Liu, Lifang He, Yong Jia, Fanli Meng, Development of sensors based on CuO-doped SnO2 hollow spheres for ppb level H2S gas sensing Journal of Materials Science. ,vol. 44, pp. 4326- 4333 ,(2009) , 10.1007/S10853-009-3645-Y
Chatchawal Wongchoosuk, Anurat Wisitsoraat, Adisorn Tuantranont, Teerakiat Kerdcharoen, Portable electronic nose based on carbon nanotube-SnO2 gas sensors and its application for detection of methanol contamination in whiskeys Sensors and Actuators B-chemical. ,vol. 147, pp. 392- 399 ,(2010) , 10.1016/J.SNB.2010.03.072
M. Mittal, A. Kumar, Carbon nanotube (CNT) gas sensors for emissions from fossil fuel burning Sensors and Actuators B-chemical. ,vol. 203, pp. 349- 362 ,(2014) , 10.1016/J.SNB.2014.05.080
Fatima E. Annanouch, Zouhair Haddi, Stella Vallejos, Polona Umek, Peter Guttmann, Carla Bittencourt, Eduard Llobet, Aerosol-Assisted CVD-Grown WO3 Nanoneedles Decorated with Copper Oxide Nanoparticles for the Selective and Humidity-Resilient Detection of H2S ACS Applied Materials & Interfaces. ,vol. 7, pp. 6842- 6851 ,(2015) , 10.1021/ACSAMI.5B00411
Fan-Na Meng, Xin-Peng Di, Hong-Wei Dong, Yue Zhang, Chun-Ling Zhu, Chunyan Li, Yu-Jin Chen, Ppb H2S gas sensing characteristics of Cu2O/CuO sub-microspheres at low-temperature Sensors and Actuators B-chemical. ,vol. 182, pp. 197- 204 ,(2013) , 10.1016/J.SNB.2013.02.112
Zongke Xu, Guotao Duan, Yue Li, Guangqiang Liu, Hongwen Zhang, Zhengfei Dai, Weiping Cai, CuO–ZnO Micro/Nanoporous Array‐Film‐Based Chemosensors: New Sensing Properties to H2S Chemistry: A European Journal. ,vol. 20, pp. 6040- 6046 ,(2014) , 10.1002/CHEM.201304722