Swelling behavior of ion exchange resins incorporated in tri-calcium silicate cement matrix: I. Chemical analysis

作者: M. Neji , B. Bary , P. Le Bescop , N. Burlion

DOI: 10.1016/J.JNUCMAT.2015.10.013

关键词: Silicate CementCementCalcium silicatePrecipitation (chemistry)PortlanditeIon-exchange resinSwellingIon exchangeChemical engineeringMaterials science

摘要: This paper presents the first part of a theoretical and experimental work aiming at modeling chemo-mechanical behavior composites made up ion exchange resins (IER) solidified in tri-calcium silicate cement paste (C3S). Because processes, volume change IER may cause internal pressures leading to degradation material. In this study, predictive is developed for describing chemical such It based on thermodynamic equilibria determine evolution potential precipitation portlandite composite. parallel, phenomenological study has been set understand phenomena related swelling mechanisms. The model created finally implemented finite elements software; simulation laboratory test performed results compared data.

参考文章(47)
D. Damidot, F.P. Glasser, Investigation of the CaO-Al2O3-SiO2-H2O system at 25°C by thermodynamic calculations Cement and Concrete Research. ,vol. 25, pp. 22- 28 ,(1995) , 10.1016/0008-8846(94)00108-B
G.W. Veazey, R.L. Ames, Cement waste-form development for ion-exchange resins at the Rocky Flats Plant Other Information: PBD: Mar 1997. ,(1997) , 10.2172/464187
Eveline Herve, Andre Zaoui, n-Layered inclusion-based micromechanical modelling International Journal of Engineering Science. ,vol. 31, pp. 1- 10 ,(1993) , 10.1016/0020-7225(93)90059-4
Masami MATSUDA, Takashi NISHI, Koich CHINO, Makoto KIKUCHI, Solidification of Spent Ion Exchange Resin Using New Cementitious Material, (I): Swelling Pressure of Ion Exchange Resin Journal of Nuclear Science and Technology. ,vol. 29, pp. 883- 889 ,(1992) , 10.1080/18811248.1992.9731608
George J. Dvorak, THERMOMECHANICS OF HETEROGENEOUS MEDIA Journal of Thermal Stresses. ,vol. 20, pp. 799- 817 ,(1997) , 10.1080/01495739708956129
Benoit Bary, Nikos Leterrier, Estelle Deville, Patrick Le Bescop, Coupled chemo-transport-mechanical modelling and numerical simulation of external sulfate attack in mortar Cement & Concrete Composites. ,vol. 49, pp. 70- 83 ,(2014) , 10.1016/J.CEMCONCOMP.2013.12.010
Manuel Carmona, Jolanta Warchoł, Antonio de Lucas, Juan F. Rodriguez, Ion-Exchange Equilibria of Pb2+, Ni2+, and Cr3+ Ions for H+ on Amberlite IR-120 Resin Journal of Chemical & Engineering Data. ,vol. 53, pp. 1325- 1331 ,(2008) , 10.1021/JE8000552
Nadia Mokni, Sebastià Olivella, Xiangling Li, Steven Smets, Elie Valcke, An Mariën, Deformation of bitumen based porous material: Experimental and numerical analysis Journal of Nuclear Materials. ,vol. 404, pp. 144- 153 ,(2010) , 10.1016/J.JNUCMAT.2010.07.019