Parameter representation of average potential energy of zero point vibrations
作者： C.P. Girijavallabhan , S. Sasidharan Nair , K. Babu Joseph
DOI: 10.1016/0022-2852(76)90240-X
关键词: Vibration 、 Mathematical analysis 、 Physics 、 Classical mechanics 、 Zero-point energy 、 Bent molecular geometry 、 Minification 、 Potential energy 、 Force field (chemistry) 、 Physical and Theoretical Chemistry 、 Spectroscopy 、 Atomic and Molecular Physics, and Optics
摘要: Abstract The variation of contributions to the average vibrational potential energy with a parameter characterizing force field has been mapped for some twenty-three bent symmetrical XY2 systems. Simple and physically significant criteria calculation extremely reliable harmonic fields are found emerge from this study. For nonhydrides minimization main bending contribution fασα hydrides quantity + 2frασrα yield excellent in agreement standard fixed help additional experimental data.
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