Study on paper-structured catalyst for direct internal reforming SOFC fueled by the mixture of CH4 and CO2

作者: Yusuke Shiratori , Teppei Ogura , Hironori Nakajima , Mio Sakamoto , Yutaro Takahashi

DOI: 10.1016/J.IJHYDENE.2013.06.046

关键词: Materials scienceSolid oxide fuel cellYttria-stabilized zirconiaCatalyst supportFiberChemical engineeringCatalysisCarbon dioxide reformingMethane reformerMethane

摘要: Abstract Inorganic fiber network including YSZ which acts as catalyst support was created by the simple paper-making process, and novel Ni-loaded paper-structured catalysts (PSCs) with excellent catalytic activity for dry reforming of methane were designed developed. The PSCs exhibited high fuel conversion comparable to conventional powdered less than one-tenth weights. significant advantages are their mechanical flexibility material workability. So far, a functionally-graded reaction field leads uniform temperature distribution during biogas resulting in stable operation planar SOFC successfully developed PSC array based on kinetic simulation model built this research.

参考文章(24)
Y SHIRATORI, Y TERAOKA, K SASAKI, Ni1−x−yMgxAlyO–ScSZ anodes for solid oxide fuel cells Solid State Ionics. ,vol. 177, pp. 1371- 1380 ,(2006) , 10.1016/J.SSI.2006.06.010
Chunchuan Xu, John W. Zondlo, Mingyang Gong, F. Elizalde-Blancas, Xingbo Liu, I.B. Celik, Tolerance tests of H2S-laden biogas fuel on solid oxide fuel cells Journal of Power Sources. ,vol. 195, pp. 4583- 4592 ,(2010) , 10.1016/J.JPOWSOUR.2010.02.078
J Staniforth, K Kendall, Biogas powering a small tubular solid oxide fuel cell Journal of Power Sources. ,vol. 71, pp. 275- 277 ,(1998) , 10.1016/S0378-7753(97)02762-6
K. Girona, J. Laurencin, J. Fouletier, F. Lefebvre-Joud, Carbon deposition in CH4/CO2 operated SOFC: Simulation and experimentation studies Journal of Power Sources. ,vol. 210, pp. 381- 391 ,(2012) , 10.1016/J.JPOWSOUR.2011.12.005
Andrea Lanzini, Pierluigi Leone, Experimental investigation of direct internal reforming of biogas in solid oxide fuel cells International Journal of Hydrogen Energy. ,vol. 35, pp. 2463- 2476 ,(2010) , 10.1016/J.IJHYDENE.2009.12.146
S FUKAHORI, H KOGA, T KITAOKA, M NAKAMURA, H WARIISHI, Steam reforming behavior of methanol using paper-structured catalysts: Experimental and computational fluid dynamic analysis International Journal of Hydrogen Energy. ,vol. 33, pp. 1661- 1670 ,(2008) , 10.1016/J.IJHYDENE.2007.12.063
Shuji Fukahori, Takuya Kitaoka, Akihiko Tomoda, Ryo Suzuki, Hiroyuki Wariishi, Methanol steam reforming over paper-like composites of Cu/ZnO catalyst and ceramic fiber Applied Catalysis A-general. ,vol. 300, pp. 155- 161 ,(2006) , 10.1016/J.APCATA.2005.11.008
H. Yakabe, T. Ogiwara, M. Hishinuma, I. Yasuda, 3-D model calculation for planar SOFC Journal of Power Sources. ,vol. 102, pp. 144- 154 ,(2001) , 10.1016/S0378-7753(01)00792-3
Y. Takahashi, Y. Shiratori, S. Furuta, K. Sasaki, Thermo-mechanical reliability and catalytic activity of Ni–Zirconia anode supports in internal reforming SOFC running on biogas Solid State Ionics. ,vol. 225, pp. 113- 117 ,(2012) , 10.1016/J.SSI.2012.03.038
A Atkinson, Mechanical behaviour of ceramic oxygen ion-conducting membranes Solid State Ionics. ,vol. 134, pp. 59- 66 ,(2000) , 10.1016/S0167-2738(00)00714-1