Mobility enhancement through homogeneous nematic alignment of a liquid-crystalline polyfluorene

作者: M. Redecker , D. D. C. Bradley , M. Inbasekaran , E. P. Woo

DOI: 10.1063/1.123563

关键词: Organic semiconductorPolyimideCondensed matter physicsHomeotropic alignmentMaterials sciencePolyfluoreneElectron mobilityOrder of magnitudeElectric fieldOrganic chemistryLiquid crystal

摘要: Homogeneous alignment of poly(9,9′-dioctylfluorene) films on rubbed polyimide results in a more than one order magnitude increase time-of-flight hole mobility normal to the direction. We find μ=8.5±1×10−3 cm2/V s at an electric field E=104 V/cm. Hole transport is found be nondispersive, indicating low degree energetic disorder.

参考文章(19)
Martin Grell, Donal DC Bradley, Mike Inbasekaran, Ed P Woo, None, A glass‐forming conjugated main‐chain liquid crystal polymer for polarized electroluminescence applications Advanced Materials. ,vol. 9, pp. 798- 802 ,(1997) , 10.1002/ADMA.19970091006
Hiroaki Tokuhisa, Masanao Era, Tetsuo Tsutsui, Polarized electroluminescence from smectic mesophase Applied Physics Letters. ,vol. 72, pp. 2639- 2641 ,(1998) , 10.1063/1.121441
A. J. Campbell, D. D. C. Bradley, D. G. Lidzey, Space-charge limited conduction with traps in poly(phenylene vinylene) light emitting diodes Journal of Applied Physics. ,vol. 82, pp. 6326- 6342 ,(1997) , 10.1063/1.366523
Norio. Miyaura, Akira. Suzuki, Palladium-catalyzed cross-coupling reactions of organoboron compounds Chemical Reviews. ,vol. 95, pp. 2457- 2483 ,(1995) , 10.1021/CR00039A007
Masahiro Funahashi, Jun-ichi Hanna, Fast ambipolar carrier transport in smectic phases of phenylnaphthalene liquid crystal Applied Physics Letters. ,vol. 71, pp. 602- 604 ,(1997) , 10.1063/1.119806
M. Grell, D.D.C. Bradley, X. Long, T. Chamberlain, M. Inbasekaran, E.P. Woo, M. Soliman, Chain geometry, solution aggregation and enhanced dichroism in the liquidcrystalline conjugated polymer poly(9,9-dioctylfluorene) Acta Polymerica. ,vol. 49, pp. 439- 444 ,(1998) , 10.1002/(SICI)1521-4044(199808)49:8<439::AID-APOL439>3.0.CO;2-A
P. M. Borsenberger, L. Pautmeier, H. Bässler, Charge transport in disordered molecular solids The Journal of Chemical Physics. ,vol. 94, pp. 5447- 5454 ,(1991) , 10.1063/1.460506
Masahiro Funahashi, Jun-ichi Hanna, Fast Hole Transport in a New Calamitic Liquid Crystal of 2-(4′-Heptyloxyphenyl)-6-Dodecylthiobenzothiazole Physical Review Letters. ,vol. 78, pp. 2184- 2187 ,(1997) , 10.1103/PHYSREVLETT.78.2184
Dirk Hertel, Ullrich Scherf, Heinz Bässler, Charge Carrier Mobility in a Ladder-Type Conjugated Polymer Advanced Materials. ,vol. 10, pp. 1119- 1122 ,(1998) , 10.1002/(SICI)1521-4095(199810)10:14<1119::AID-ADMA1119>3.0.CO;2-K
C. W. Tang, Two‐layer organic photovoltaic cell Applied Physics Letters. ,vol. 48, pp. 183- 185 ,(1986) , 10.1063/1.96937