Study of the extraction of gold(III) in aqueous hydrochloric acid media by the phosphine oxide Cyanex 925

作者: M.A. Barroso , F.A. López , A. Sastre , F.J. Alguacil

DOI: 10.1016/S0304-386X(96)00080-1

关键词: Hydrochloric acidChemistryPhosphine oxideStripping (chemistry)DiluentGold extractionAqueous solutionInorganic chemistryStoichiometryExtraction (chemistry)

摘要: Abstract The extraction of gold(III) from hydrochloric acid solutions by means the phosphine oxide Cyanex 925 was studied as a function different variables: equilibration time, temperature, organic diluent, and concentration gold, 925, HCl, etc.; system is selective with respect to number metals. Gold(III) equilibrium loading isotherms were also obtained at 20°C. Experimental data treated numerically showing that gold can be explained assuming formation complex general stoichiometry: HAuCl 4 L 2 , where represents extractant. For reaction log K ext o = 8.1. stripping loaded phases achieved water. Data on HCl are presented.

参考文章(18)
A. W. Ashbrook, G. M. Ritcey, Solvent extraction : principles and applications to process metallurgy Published in <b>1984</b> in Amsterdam by Elsevier. ,(1979)
Jan Rydberg, Claude Musikas, Gregory R. Choppin, Principles and practices of solvent extraction M. Dekker. ,(1992)
Iain House, John Marsden, The chemistry of gold extraction ,(1969)
Carl Hanson, Teh C. Lo, Malcolm H. I. Baird, Handbook of Solvent Extraction ,(1991)
D. H. Logsdail, M. J. Slater, Solvent extraction in the process industries Elsevier Applied Science. ,(1993)
C. K. Gupta, T. K. Mukherjee, Hydrometallurgy in Extraction Processes CRC Press. ,(2019) , 10.1201/9780203751428
J. C. Yannopoulos, The extractive metallurgy of gold ,(1990)
F.J. Alguacil, F.A. López, The extraction of mineral acids by the phosphine oxide Cyanex 923 Hydrometallurgy. ,vol. 42, pp. 245- 255 ,(1996) , 10.1016/0304-386X(95)00101-L
I. Villaescusa, N. Miralles, J. de Pablo, V. Salvado, A.M. Sastre, EXTRACTION OF GOLD(III) FROM HYDROCHLORIC ACID SOLUTIONS BY Tri-n-DODECYLAMMONIUM CHLORIDE IN TOLUENE. ESTIMATION OF THE INTERACTION COEFFICIENT BETWEEN AuCl4 and H+. Solvent Extraction and Ion Exchange. ,vol. 11, pp. 613- 626 ,(1993) , 10.1080/07366299308918177