Synthesis, Magneto-Spectral and Thermal Studies of Cobalt(II) and Nickel(II) Complexes of 4-[N-(4-Dimethylaminobenzylidene) amino] Antipyrine

作者: RK Agarwal , Priyanka Garg , Himanshu Agarwal , Sulekh Chandra , None

DOI: 10.1080/00945719708000150

关键词: NickelOxygenInfrared spectroscopyCrystallographyInorganic chemistryCobaltChemistryLigandNitrogen

摘要: Abstract Reactions of MX2 (M = Co or Ni, X C1−, Br−, I−, NO− 3, NCS−, C1O− 4) with 4-[N-(4-dimethylaminobenzylidene) -amino] antipyrine (DABAAP) yielded complexes the type [M(DABAAP)2X2] [M(DABAAP) 3](C1O4)2. The IR spectra these indicate that ligand is a neutral bidentate coordinating through azomethine nitrogen and carbonyl oxygen. All are six coordinated according data magnetic electronic spectral measurements. Referee I: Y. Fukuda II: S. Yamada

参考文章(18)
Frank Johnson Welcher, The analytical uses of ethylenediamine tetraacetic acid Van Nostrand. ,(1958)
John R. Ferraro, The nitrate symmetry in metallic nitrates Journal of Molecular Spectroscopy. ,vol. 4, pp. 99- 105 ,(1960) , 10.1016/0022-2852(60)90071-0
S Yamada, Recent aspects of the stereochemistry of schiff-base-metal complexes Coordination Chemistry Reviews. ,vol. 1, pp. 415- 437 ,(1966) , 10.1016/S0010-8545(00)80184-8
A.B.P. Lever, The electronic spectra of tetragonal metal complexes analysis and significance Coordination Chemistry Reviews. ,vol. 3, pp. 119- 140 ,(1968) , 10.1016/S0010-8545(00)80107-1
B. J. Hathaway, A. E. Underhill, 592. The infrared spectra of some transition-metal perchlorates Journal of the Chemical Society (Resumed). pp. 3091- 3096 ,(1961) , 10.1039/JR9610003091
R. A. Bailey, T. R. Peterson, Complexes of Co(II), Ni(II), and Zn(II) with pyrazolone ligands Canadian Journal of Chemistry. ,vol. 47, pp. 1681- 1687 ,(1969) , 10.1139/V69-276
John L. Burmeister, Recent developments in the coordination chemistry of ambidentate ligands Coordination Chemistry Reviews. ,vol. 1, pp. 205- 221 ,(1966) , 10.1016/S0010-8545(00)80174-5
A. B. P. Lever, S. M. Nelson, T. M. Shepherd, An Analysis of the Electronic Spectra of Some Nickel(II) Halide Amine Complexes Inorganic Chemistry. ,vol. 4, pp. 810- 813 ,(1965) , 10.1021/IC50028A008
G. Shankar, R.R. Premkumar, S.K. Ramalingam, 4-Aminoantipyrine schiff-base complexes of lanthanide and uranyl ions Polyhedron. ,vol. 5, pp. 991- 994 ,(1986) , 10.1016/S0277-5387(00)80140-0
R. K. Agarwal, Gyanendra Singh, Preparation, Spectral and Thermal Studies of Some Oxovanadium (IV) Complexes of 4-Aminoantipyrine Synthesis and Reactivity in Inorganic and Metal-organic Chemistry. ,vol. 16, pp. 1183- 1196 ,(1986) , 10.1080/00945718608071390