Temperature‐dependent study of carbon‐13 spin‐lattice relaxation times in para ‐azoxyanisole‐A nematic liquid crystal

作者: M. Schwartz , P. E. Fagerness , C. H. Wang , D. M. Grant

DOI: 10.1063/1.1681023

关键词: CrystallographyRing (chemistry)ProtonThermodynamicsTransition temperaturepara-AzoxyanisoleSpin–lattice relaxationCarbon-13Relaxation (physics)ChemistryLiquid crystal

摘要: The 13C spin‐lattice relaxation times of both the ring and methyl carbons in liquid crystal, p‐azoxydianisole, are reported as a function temperature on sides clearing point. In marked contrast to earlier results proton relaxation, were found exhibit no noticeable discontinuity at nematic‐isotropic transition temperature. explained by comparing mechanisms influencing carbon‐13 T1's those present for relaxation.

参考文章(19)
James R. Lyerla, David M. Grant, C. H. Wang, Carbon‐13 Spin—Rotational Relaxation in CH3I and CH3CN The Journal of Chemical Physics. ,vol. 55, pp. 4676- 4677 ,(1971) , 10.1063/1.1676821
Ronald Y. Dong, M. Marušič, C.F. Schwerdtfeger, Correlated NMR and EPR studies in a nematic liquid crystal Solid State Communications. ,vol. 8, pp. 1577- 1581 ,(1970) , 10.1016/0038-1098(70)90612-5
L. D. Colebrook, J. A. Jahnke, A nuclear magnetic resonance study of hindered rotation in biphenyls. Podototarin diacetate and podototarin dimethyl ether Journal of the American Chemical Society. ,vol. 90, pp. 4687- 4690 ,(1968) , 10.1021/JA01019A032
B. Deloche, B. Cabane, Coupling of Hydrogen Bonding to Orientational Fluctuation Modes in the Liquid Crystal PHBA Molecular Crystals and Liquid Crystals. ,vol. 19, pp. 25- 61 ,(1972) , 10.1080/15421407208083852
J.W. Doane, D.L. Johnson, Spin-lattice relaxation in the nematic liquid crystalline phase Chemical Physics Letters. ,vol. 6, pp. 291- 295 ,(1970) , 10.1016/0009-2614(70)85078-3
Kenneth T. Gillen, Martin Schwartz, Joseph H. Noggle, N.M.R. relaxation time studies in liquid methyl iodide Molecular Physics. ,vol. 20, pp. 899- 912 ,(1971) , 10.1080/00268977100100871
J. C. Rowell, W. D. Phillips, L. R. Melby, M. Panar, NMR Studies of Some Liquid Crystal Systems Journal of Chemical Physics. ,vol. 43, pp. 3442- 3454 ,(1965) , 10.1063/1.1696498
Charles S. Johnson, Charles L. Watkins, Nuclear spin relaxation in nematic liquid crystals The Journal of Physical Chemistry. ,vol. 75, pp. 2452- 2458 ,(1971) , 10.1021/J100685A007
P Pincus, Nuclear relaxation in a nematic liquid crystal Solid State Communications. ,vol. 7, pp. 415- 417 ,(1969) , 10.1016/0038-1098(69)90886-2
R. Blinc, D. L. Hogenboom, D. E. O'Reilly, E. M. Peterson, Spin Relaxation and Self-Diffusion in Liquid Crystals Physical Review Letters. ,vol. 23, pp. 969- 972 ,(1969) , 10.1103/PHYSREVLETT.23.969