Synthesis and crystal structure of three-coordinated silver(I) and copper(I) complexes with N2P binding set containing a novel tripodal ligand: 1,3,5-tris(benzimidazol-2-ylmethyl)benzene
作者： Wei-Yin Sun , Jin Xie , Yu-Hua Mei , Kai-Bei Yu
DOI: 10.1039/B002450N
关键词: Triphenylphosphine 、 Copper 、 Tris 、 Stereochemistry 、 Ligand 、 Tripodal ligand 、 Crystal structure 、 Crystallography 、 Chemistry 、 Atom 、 Benzene
摘要: Assembly of a novel tripodal ligand, 1,3,5-tris(benzimidazol-2-ylmethyl)benzene (tbib), and triphenylphosphine with silver(I) copper(I) salts gave the corresponding mononuclear complexes, which were characterized by electrospray mass spectrometry 31P NMR spectroscopy. The structure complex, [Ag(tbib)(PPh3)]NO3 ·CH3OH·H2O, determined X-ray crystallography, indicates that atom is coordinated two nitrogen atoms one tbib ligand phosphorus triphenylphosphine. Another is uncoordinated. complex provides another example structurally characterized complex N2P binding set.
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Laurence K. Thompson, Baratham S. Ramaswamy, Elizabeth A. Seymour, Cobalt(II) and zinc(II) complexes of the 'tripod' ligand tris(2-benzimidazylmethyl)amine. Some five-coordinate derivatives and some with mixed stereochemistries Canadian Journal of Chemistry. ,vol. 55, pp. 878- 888 ,(1977) , 10.1139/V77-122
Daniel. Carmona, Fernando J. Lahoz, Luis A. Oro, Maria Pilar. Lamata, Susana. Buzarra, (Pentamethylcyclopentadienyl)bis(pyrazolato)(pyrazole)iridium(III) as a metal-complex ligand. Synthesis, characterization, and reactivity of heterodinuclear IrM [M = copper(I), silver(I), gold(I), rhodium(I)] and heterotrinuclear IrAg2 and IrRhAg derivatives Organometallics. ,vol. 10, pp. 3123- 3131 ,(1991) , 10.1021/OM00055A028
Makoto Fujita, Daichi Oguro, Mayumi Miyazawa, Hiroko Oka, Kentaro Yamaguchi, Katsuyuki Ogura, Self-assembly of ten molecules into nanometre-sized organic host frameworks Nature. ,vol. 378, pp. 469- 471 ,(1995) , 10.1038/378469A0
Geoffrey B. Gardner, D. Venkataraman, Jeffrey S. Moore, Stephen Lee, Spontaneous assembly of a hinged coordination network Nature. ,vol. 374, pp. 792- 795 ,(1995) , 10.1038/374792A0
L Hong-Ke, S Wei-Yin, T Wen-Xia, T Yamamoto, N Ueyama, Self-Assembly of the First Copper(II) Infinite 2D Network with Large Cavities Formed between the Two Adjacent Layers. Inorganic Chemistry. ,vol. 38, pp. 6313- 6316 ,(1999) , 10.1021/IC9907563
Yuan Yao, Marc W. Perkovic, D. Paul Rillema, Clifton Woods, Structures and properties of copper(II) and copper(I) complexes containing an ethane-bridged dimeric phenanthroline ligand Inorganic Chemistry. ,vol. 31, pp. 3956- 3962 ,(1992) , 10.1021/IC00045A019
G. Attilio Ardizzoia, Girolamo La Monica, Angelo Maspero, Massimo Moret, Norberto Masciocchi, Silver(I) Pyrazolates. Synthesis and X-ray and 31P-NMR Characterization of Triphenylphosphine Complexes and Their Reactivity toward Heterocumulenes Inorganic Chemistry. ,vol. 36, pp. 2321- 2328 ,(1997) , 10.1021/IC960908J
Marie Therese. Youinou, Raymond. Ziessel, Jean Marie. Lehn, Formation of dihelicate and mononuclear complexes from ethane-bridged dimeric bipyridine or phenanthroline ligands with copper(I), cobalt(II), and iron(II) cations Inorganic Chemistry. ,vol. 30, pp. 2144- 2148 ,(1991) , 10.1021/IC00009A035
Olga Crespo, M.Concepción Gimeno, Antonio Laguna, Synthesis and reactivity of the ligand 1,2-bis(pyridine-2-ylthio)-1,2-dicarba-closo-dodecaborane. Crystal structure of [Ag{1,2-(C5H4NS)2-1,2-C2B10H10}(PPh3)]OTf Journal of Organometallic Chemistry. ,vol. 561, pp. 13- 18 ,(1998) , 10.1016/S0022-328X(98)00501-4
Hong-Ke Liu, Wei-Yin Sun, Hai-Liang Zhu, Kai-Bei Yu, Wen-Xia Tang, A two-dimensional network constructed via 72-membered heart-shaped macrocycles, a copper(II) complex with 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene and diethylenetriamine ligands Inorganica Chimica Acta. ,vol. 295, pp. 129- 135 ,(1999) , 10.1016/S0020-1693(99)00332-1