Analysis of the product streams obtained on butanosolv pretreatment of draff

作者: Flora Foltanyi , Julie E. Hawkins , Isabella Panovic , Eve J. Bird , Tracey M. Gloster

DOI: 10.1016/J.BIOMBIOE.2020.105680

关键词: FermentationHemicelluloseLigninChemistryMonosaccharideEnzymatic hydrolysisChromatographyHydrolysisXylosePulp (paper)

摘要: Abstract The efficient use of biomass-derived waste streams from the food and drink industry is very important for achieving a circular economy. In this work, pretreatment based on 1-butanol (butanosolv) was used to fractionate draff, by-product brewing distilling industries, leading solid pulp, hemicellulose derived-fraction pseudo lignin. pulp enriched in glucans showed 4-fold improvement enzymatic hydrolysis experiments relative starting biomass. could be fermented an ABE process producing 32g/100g solvents. hemicellulose-derived fraction analysed by 2D HSQC NMR found contain mixture predominantly butoxylated monosaccharides. hydrolase enzymes present Cellic® CTec3 were hydrolyse selectively glucose xylose derived butyl β-pyranose monomers. Alternatively, non-selective both anomers achieved using TFA/H2O giving native sugars fermentation recovered 1-butanol. A detailed characterization lignin also achieved.

参考文章(53)
Patrick R. Gruber, Michael Kamm, Birgit Kamm, Biorefineries - industrial processes and products : status quo and future directions Wiley-VCH. ,(2006)
Asad S.N. Mahmood, John G. Brammer, Andreas Hornung, Andrew Steele, Stephen Poulston, The intermediate pyrolysis and catalytic steam reforming of brewers spent grain Journal of Analytical and Applied Pyrolysis. ,vol. 103, pp. 328- 342 ,(2013) , 10.1016/J.JAAP.2012.09.009
Erzheng Su, Dongzhi Wei, Production of fatty acid butyl esters using the low cost naturally immobilized Carica papaya lipase. Journal of Agricultural and Food Chemistry. ,vol. 62, pp. 6375- 6381 ,(2014) , 10.1021/JF501993V
Athina Lazaridou, Tricia Chornick, Costas G. Biliaderis, Marta S. Izydorczyk, Composition and molecular structure of polysaccharides released from barley endosperm cell walls by sequential extraction with water, malt enzymes, and alkali Journal of Cereal Science. ,vol. 48, pp. 304- 318 ,(2008) , 10.1016/J.JCS.2007.09.011
Nicole G. Grobben, Gerrit Eggink, F. Petrus Cuperus, Henk J. Huizing, Production of acetone, butanol and ethanol (ABE) from potato wastes: fermentation with integrated membrane extraction Applied Microbiology and Biotechnology. ,vol. 39, pp. 494- 498 ,(1993) , 10.1007/BF00205039
Paul V Harris, Feng Xu, Nathaniel E Kreel, Connie Kang, Shiro Fukuyama, New enzyme insights drive advances in commercial ethanol production. Current Opinion in Chemical Biology. ,vol. 19, pp. 162- 170 ,(2014) , 10.1016/J.CBPA.2014.02.015
M. Galbe, G. Zacchi, A review of the production of ethanol from softwood Applied Microbiology and Biotechnology. ,vol. 59, pp. 618- 628 ,(2002) , 10.1007/S00253-002-1058-9
Xiaojuan Ma, Xuefang Yang, Xin Zheng, Lihui Chen, Liulian Huang, Shilin Cao, Hannah Akinosho, Toward a further understanding of hydrothermally pretreated holocellulose and isolated pseudo lignin Cellulose. ,vol. 22, pp. 1687- 1696 ,(2015) , 10.1007/S10570-015-0607-1
Anette Skammelsen Schmidt, Anne Belinda Thomsen, Optimization of wet oxidation pretreatment of wheat straw Bioresource Technology. ,vol. 64, pp. 139- 151 ,(1998) , 10.1016/S0960-8524(97)00164-8