Organic Synthesis Highlights

摘要: Preface.List of Contributors.PART I. SYNTHETIC METHODS.Direct Conversion Sugar Glycosides into Carbocycles (Peter Dalko and Pierre Sinay).Synthesis Diaryl Ethers: A Long-Standing Problem Has Been Solved (Fritz Theil).Take The Right Catalyst: Palladium-Catalyzed CC-, CN- CO-Bond Formation on Chloro-Arenes (Rainer Stumer).Alkyne Metathesis in Natural Product Synthesis (Thomas Lindel).Transition Metal-Catalyzed Functionalization Alkanes (Oliver Seitz).An Eldorado for Homogeneous Catalysis? (Gerald Dyker).New Selective Transition Metal Catalyzed Reactions Allenes (A. Stephen K. Hashmi).Controlling Stereoselectivity with the Aid a Reagent-Directing Group (Bernhard Breit).Solvent-Free Organic Syntheses (Jurgen O. Metzger).Fluorous Techniques: Progress Reaction-Processing Purification (Ulf Diederichsen).Recent Developments Using Ionic Liquids as Solvents Catalysts Wasserscheid).Recent Advances Sharpless Asymmetric Aminohydroxylation (Dmitry Nilov Oli ver Reiser).Asymmetric Phase Transfer Catalysis (Christabel Carter Adam Nelson).Asymmetric Catalytic Aminoalkylations: New Powerful Methods Enantioselective Amino Acid Derivatives, Mannich Bases, Homoallylic Amines (Michael Arend Xiaojing Wang).IBX - an Old Reagent Wirth).Parallel Kinetic Resolutions (Jason Eames).The Baylis-Hillman-Reaction Langer).Simple Acids Short-Chain Peptides Efficient Metal-free (Harald Groger, et al.).Recent Strecker-Type (Larry Yet).Highly or Not? Chiral Monodentate Monophosphorus Ligands Hydrogenation (Igor V. Komarov Armin Borner).Improving Fluorination Reactions: N-Fluoro Ammonium Salts (Kilian Muniz).Catalytic Olefin (Amir H. Hoveyda Richard R. Schrock).Activating Protecting Groups Solid Modification Peptides, Oligonucleotides Oligosaccharides Seitz).Traceless Linkers Solid-Phase (Florencio Zaragoza Dorwald).Merging Solution-Phase Synthesis: "Resin-Capture- Release" Hybrid Technique (Andreas Kirschning Rudiger Wittenberg).Polymeric Scavenger Reagents Eames Michael Watkinson).PART II. APPLICATIONS.Total Vancomycin (Lars Thoresen Kevin Burgess).Bryostatin Their Analogues Diederichsen).Eleutherobin: Synthesis, Structure/Activity Relationship, Pharmacophore Diederichsen).Total Products CP-263,114 CP-225,917 Diederichsen Katrin B. Lorenz).Polyene Cyclization to Adociasulfate 1 Lindel Cordula Hopmann).Sanglifehrin A: An Immunosuppressant from Malawi Lindel).Short Spirotryprostatins Lindel).The Chemical Total Proteins Seitz).Solid-Phase Thomas Wagner).Polymer-Supported Non-Oligomeric (Stefan Sommer, al.).Explosions Synthetic Tool? Cycloalkynes Precursors Fullerenes, Buckytubes Buckyonions (Rudiger Faust).Dendralenes: From Neglected Class Polyenes Versatile Starting Materials (Henning Hopf).Fascinating Artificial Cyclopropane Architectures Faust).Index.