Probing Gas Adsorption in Zeolites by Variable-Temperature IR Spectroscopy: An Overview of Current Research
作者： Edoardo Garrone , Montserrat R. Delgado , Barbara Bonelli , Carlos O. Arean
DOI: 10.3390/MOLECULES22091557
关键词: Infrared spectroscopy 、 Chemistry 、 Gas separation 、 Spectroscopy 、 Inorganic chemistry 、 Calorimetry 、 Heterogeneous catalysis 、 Standard enthalpy of formation 、 Adsorption 、 Interaction energy
摘要: The current state of the art in application variable-temperature IR (VTIR) spectroscopy to study (i) adsorption sites zeolites, including dual cation sites; (ii) structure complexes and (iii) gas-solid interaction energy is reviewed. main focus placed on potential use zeolites for gas separation, purification transport, but possible extension field heterogeneous catalysis also envisaged. A critical comparison with classical calorimetry shows that merits VTIR are its ability provide simultaneously spectroscopic signature complex standard enthalpy change involved process; enhanced be site specific favorable cases.
mdpi.com
core.ac.uk 
sci-hub.se 参考文章(77)
Griselda Eimer, Pedro Girola, Lorena Tomas, Liliana Pierella, Oscar Anunziata, Catalytic Activity of MEL Zeolites Modified with Metallic Couples for the Conversion of Ethane Molecules. ,vol. 5, pp. 560- 561 ,(2000) , 10.3390/50300560
C. Otero Areán, M. Rodríguez Delgado, K. Frolich, R. Bulánek, A. Pulido, G. Fiol Bibiloni, P. Nachtigall, Computational and Fourier Transform Infrared Spectroscopic Studies on Carbon Monoxide Adsorption on the Zeolites Na-ZSM-5 and K-ZSM-5: Evidence of Dual-Cation Sites Journal of Physical Chemistry C. ,vol. 112, pp. 4658- 4666 ,(2008) , 10.1021/JP7109934
Banglin Chen, Shengchang Xiang, Guodong Qian, Metal−Organic Frameworks with Functional Pores for Recognition of Small Molecules Accounts of Chemical Research. ,vol. 43, pp. 1115- 1124 ,(2010) , 10.1021/AR100023Y
Peng Tian, Yingxu Wei, Mao Ye, Zhongmin Liu, Methanol to Olefins (MTO): From Fundamentals to Commercialization ACS Catalysis. ,vol. 5, pp. 1922- 1938 ,(2015) , 10.1021/ACSCATAL.5B00007
AA Tsyganenko, P Yu Storozhev, C Otero Areán, None, IR-Spectroscopic Study of the Binding Isomerism of Adsorbed Molecules Kinetics and Catalysis. ,vol. 45, pp. 530- 540 ,(2004) , 10.1023/B:KICA.0000038081.43384.56
Pascal D. C. Dietzel, Rune E. Johnsen, Helmer Fjellvåg, Silvia Bordiga, Elena Groppo, Sachin Chavan, Richard Blom, Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal–organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction Chemical Communications. pp. 5125- 5127 ,(2008) , 10.1039/B810574J
Nadzeya V. Beznis, Bert M. Weckhuysen, Johannes H. Bitter, Cu-ZSM-5 Zeolites for the Formation of Methanol from Methane and Oxygen: Probing the Active Sites and Spectator Species Catalysis Letters. ,vol. 138, pp. 14- 22 ,(2010) , 10.1007/S10562-010-0380-6
Yong Yan, Sihai Yang, Alexander J. Blake, Martin Schröder, Studies on metal-organic frameworks of Cu(II) with isophthalate linkers for hydrogen storage. Accounts of Chemical Research. ,vol. 47, pp. 296- 307 ,(2014) , 10.1021/AR400049H
Rahul Banerjee, Yegor Proshlyakov, John D. Lipscomb, Denis A. Proshlyakov, Structure of the key species in the enzymatic oxidation of methane to methanol Nature. ,vol. 518, pp. 431- 434 ,(2015) , 10.1038/NATURE14160
A. Zecchina, C. Otero Areán, Diatomic molecular probes for mid-IR studies of zeolites Chemical Society Reviews. ,vol. 25, pp. 187- 197 ,(1996) , 10.1039/CS9962500187