Impedance and modulus spectroscopy characterization of La+3/Mn+4 modified PbTiO3 nanoceramics
作者： Archana Shukla , R.N.P. Choudhary
DOI: 10.1016/J.CAP.2010.08.014
关键词: Spectroscopy 、 Atmospheric temperature range 、 Analytical chemistry 、 Nanocrystalline material 、 Dielectric spectroscopy 、 Ceramic 、 Materials science 、 Electrical impedance 、 Tetragonal crystal system 、 Grain boundary
摘要: Abstract Nanocrystalline samples of Pb0.92La0.08MnxTi1-xO3 (PLMT) (x = 0, 0.04, 0.07, 0.10) were prepared by a high-energy ball-milling followed solid-state reaction method. Preliminary high resolution X-ray diffraction technique PLMT ceramics showed that single-phase was formed exhibiting tetragonal crystal structure. The electrical behavior investigated the impedance spectroscopy in temperature range 35 °C–500 °C. This study carried out means simultaneous analysis complex (Z∗) and modulus (M∗) functions from measurement 1 kHz–1 MHz. A separation grain boundary properties has been achieved using an equivalent circuit model analysis. Loss spectra reveal about presence temperature-dependent relaxation phenomena materials. Modulus provides wider information related to charge transport processes.
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O. Raymond, R. Font, N. Suárez-Almodovar, J. Portelles, J. M. Siqueiros, Frequency-temperature response of ferroelectromagnetic Pb(Fe1∕2Nb1∕2)O3 ceramics obtained by different precursors. Part II. Impedance spectroscopy characterization Journal of Applied Physics. ,vol. 97, pp. 084108- ,(2005) , 10.1063/1.1870100
A. R. James, S. Priya, K. Uchino, K. Srinivas, Dielectric spectroscopy of Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystals Journal of Applied Physics. ,vol. 90, pp. 3504- 3508 ,(2001) , 10.1063/1.1401802
G Sheng, JX Zhang, YL Li, S Choudhury, QX Jia, ZK Liu, LQ Chen, None, Domain stability of PbTiO3 thin films under anisotropic misfit strains: Phase-field simulations Journal of Applied Physics. ,vol. 104, pp. 054105- ,(2008) , 10.1063/1.2974093
C. H. Ahn, J.-M. Triscone, J. Mannhart, Electric field effect in correlated oxide systems Nature. ,vol. 424, pp. 1015- 1018 ,(2003) , 10.1038/NATURE01878
Bernard Dennis Cullity, Elements of X-ray diffraction ,(1956)
P. Venkateswarlu, Apurba Laha, S.B. Krupanidhi, AC properties of laser ablated La-modified lead titanate thin films Thin Solid Films. ,vol. 474, pp. 1- 9 ,(2005) , 10.1016/J.TSF.2004.02.101
Mohammad A. Alim, Admittance—Frequency Response in Zinc Oxide Varistor Ceramics Journal of the American Ceramic Society. ,vol. 72, pp. 28- 32 ,(1989) , 10.1111/J.1151-2916.1989.TB05948.X
J Maier, Defect chemistry and ion transport in nanostructured materials: Part II. Aspects of nanoionics Solid State Ionics. ,vol. 157, pp. 327- 334 ,(2003) , 10.1016/S0167-2738(02)00229-1
Zhen Zhang, Ping Wu, Khuong P. Ong, Li Lu, Chang Shu, Electronic properties of A-site substituted lead zirconate titanate: Density functional calculations Physical Review B. ,vol. 76, pp. 125102- ,(2007) , 10.1103/PHYSREVB.76.125102
Shrabanee Sen, R. N. P. Choudhary, Abhijit Tarafdar, P. Pramanik, Impedance spectroscopy study of strontium modified lead zirconate titanate ceramics Journal of Applied Physics. ,vol. 99, pp. 124114- ,(2006) , 10.1063/1.2206850