Studies of the local structures of molten metal halides

作者: Anne-Laure Rollet , Mathieu Salanne

DOI: 10.1039/C1PC90003J

关键词: Molten metalHalideShell (structure)Range (particle radiation)Chemical physicsLocal structureChemistryRare earthNanotechnologyLength scale

摘要: This review covers the local structure of molten metal halide, where a somewhat wide definition “local structure” is employed, i.e. from first shell interacting neighbours up to correlations arising at nanometer length scale. These particular liquids are indeed strongly organized unusually long distances due predominance coulombic interactions. Many them also characterized by formation intermediate range ordering. It therefore impossible describe these omitting this longer-ranged correlation. Finally, deeper attention given systems on which recent progresses have been made in last decade, as for instance fluorides and rare earth halides.

参考文章(223)
Ç. Tasseven, J. Trullàs, O. Alcaraz, M. Silbert, A. Giró, Static structure and ionic transport in molten AgBr and AgCl The Journal of Chemical Physics. ,vol. 106, pp. 7286- 7294 ,(1997) , 10.1063/1.473690
Patrick Masset, Iodide-based electrolytes: A promising alternative for thermal batteries Journal of Power Sources. ,vol. 160, pp. 688- 697 ,(2006) , 10.1016/J.JPOWSOUR.2005.12.091
G.D. Zissi, A. Chrissanthopoulos, G.N. Papatheodorou, Vibrational modes and structure of the LaCl3CsCl melts Vibrational Spectroscopy. ,vol. 40, pp. 110- 117 ,(2006) , 10.1016/J.VIBSPEC.2005.07.005
Ben Morgan, Paul A. Madden, Ion mobilities and microscopic dynamics in liquid (Li,K)Cl Journal of Chemical Physics. ,vol. 120, pp. 1402- 1413 ,(2004) , 10.1063/1.1629076
István T. Horváth, Solvents from nature Green Chemistry. ,vol. 10, pp. 1024- 1028 ,(2008) , 10.1039/B812804A
Santiago Aparicio, Rafael Alcalde, Characterization of two lactones in liquid phase: an experimental and computational approach Physical Chemistry Chemical Physics. ,vol. 11, pp. 6455- 6467 ,(2009) , 10.1039/B823507D
Y S Badyal, R A Howe, Structural modification in molten metal chloride and alkali chloride mixtures Journal of Physics: Condensed Matter. ,vol. 5, pp. 7189- 7202 ,(1993) , 10.1088/0953-8984/5/39/007
P. A. Madden, K. O’Sullivan, J. A. Board, P. W. Fowler, Light scattering by alkali halide melts: A computer simulation study Journal of Chemical Physics. ,vol. 94, pp. 918- 927 ,(1991) , 10.1063/1.459982
Mauro C. C. Ribeiro, Chemla Effect in Molten LiCl/KCl and LiF/KF Mixtures Journal of Physical Chemistry B. ,vol. 107, pp. 4392- 4402 ,(2003) , 10.1021/JP027261A
Anuj K. Chandel, G. Chandrasekhar, Messias Borges Silva, Silvio Silvério da Silva, The realm of cellulases in biorefinery development Critical Reviews in Biotechnology. ,vol. 32, pp. 187- 202 ,(2012) , 10.3109/07388551.2011.595385