Effect of pH and Ionic Strength on the Mechanism of Association of Rodenticides with Natural Organic Components of Soil

作者: C. Andr� , T.T. Truong , A. Xicluna , M. Thomassin , Y.C. Guillaume

DOI: 10.1365/S10337-005-0503-1

关键词: SolventLangmuirInorganic chemistryIonic strengthSoil waterChromatographyAdsorptionChemistryHumic acidMoleculeOrganic matter

摘要: The mechanisms of association hydrophobic organic contaminants with natural matter (for example humic acid, HA) in soil and sediment are a major objective environmental geochemical research. This paper discusses general model for studying the process between series rodenticides by use C18 stationary phase. An approach based on extended Langmuir distribution isotherms was used to study effect bulk solvent pH ionic strength (adjusted addition sodium cation) mechanism HA–rodenticide binding. results demonstrated that: (i) HA can be adsorbed surface phase; (ii) associated surface; (iii) both modify conformation thus its rodenticide molecules.

参考文章(33)
Garrison Sposito, The surface chemistry of soils ,(1984)
M J Fasco, L M Principe, R- and S-Warfarin inhibition of vitamin K and vitamin K 2,3-epoxide reductase activities in the rat Journal of Biological Chemistry. ,vol. 257, pp. 4894- 4901 ,(1982) , 10.1016/S0021-9258(18)34610-6
C. D. S. Tomlin, The Pesticide Manual The pesticide manual. pp. 1344- ,(2003)
Masanobu Janado, Yuki Yano, Miyuki Umura, Y�taro Kondo, Differential interactions of cyclodextrins with hydrophobic derivatives of sepharose Cl-4B Journal of Solution Chemistry. ,vol. 24, pp. 587- 600 ,(1995) , 10.1007/BF00973209
R. S. CAMERON, B. K. THORNTON, R. S. SWIFT, A. M. POSNER, MOLECULAR WEIGHT AND SHAPE OF HUMIC ACID FROM SEDIMENTATION AND DIFFUSION MEASUREMENTS ON FRACTIONATED EXTRACTS European Journal of Soil Science. ,vol. 23, pp. 394- 408 ,(1972) , 10.1111/J.1365-2389.1972.TB01670.X
Baohua. Gu, Juergen. Schmitt, Zhihong. Chen, Liyuan. Liang, John F. McCarthy, Adsorption and desorption of natural organic matter on iron oxide: mechanisms and models. Environmental Science & Technology. ,vol. 28, pp. 38- 46 ,(1994) , 10.1021/ES00050A007
Ravi Ranatunga, Mark F. Vitha, Peter W. Carr, Mechanistic implications of the equality of compensation temperatures in chromatography Journal of Chromatography A. ,vol. 946, pp. 47- 49 ,(2002) , 10.1016/S0021-9673(01)01539-4
James A Kruse, Richard W Carlson, Fatal rodenticide poisoning with brodifacoum Annals of Emergency Medicine. ,vol. 21, pp. 331- 336 ,(1992) , 10.1016/S0196-0644(05)80900-X