Conformational energy calculations on alginic acid. II. Conformational statistics of the copolymers

作者: S. G. Whittincjton

DOI: 10.1002/BIP.360100915

关键词: Ionic strengthConformational energyPolymer chemistryCopolymerChemistryAlginic acidPhysical chemistry

摘要: Conformational energy maps have been calculated for α-D-mannuronic acid (1–4) α-L-guluronic and β-D-mannuronic acid. These used, together with previously the homomonomeric dimers, to estimate characteristic ratios Kuhn lengths of alternating copolymer a stochastic similar in composition that extracted from L. digitata.The results show is less extended than either homopolymer. agree well experimental on high ionic strength solutions alginate isolated L digitata.

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