Solid-State Chemistry: A A Rediscovered Chemical Frontier
作者： F. J. DiSalvo
DOI: 10.1126/SCIENCE.247.4943.649
关键词: Nanotechnology 、 Chemical preparation 、 Solid-state chemistry 、 Molecule 、 Solid-state 、 New materials 、 Chemistry
摘要: Chemical bonding in solids is not completely understood, mainly because of the wide variation chemical properties elements. Many difficult challenges remain predicting composition, structure, and new materials. Consequently, synthesis novel as much an art a science. Discoveries compounds structure types highlight versatility that nature has allowed with relatively small number This article explores long-term solid-state chemistry then focuses on efforts at Cornell to prepare solids.
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Robin P. Ziebarth, John D. Corbett, Isolated zirconium chloride clusters in the phase Rb5Zr6Cl18B. Generalities regarding the bonding, stability and size of M6X12-type clusters with and without interstitial atoms Journal of the American Chemical Society. ,vol. 111, pp. 3272- 3280 ,(1989) , 10.1021/JA00191A025
Robert W. Seidel, How the military responded to the laser Physics Today. ,vol. 41, pp. 36- 43 ,(1988) , 10.1063/1.881156
R. Pool, Good news for superconductors. Science. ,vol. 246, pp. 755- 755 ,(1989) , 10.1126/SCIENCE.246.4931.755
T. H. GEBALLE, J. K. HULM, Superconductivity—The State That Came in from the Cold Science. ,vol. 239, pp. 367- 375 ,(1988) , 10.1126/SCIENCE.239.4838.367
R. Pool, Superconductivity: Is the Party Over? Science. ,vol. 244, pp. 914- 916 ,(1989) , 10.1126/SCIENCE.244.4907.914
Leo Goldberg, Atomic Spectroscopy and Astrophysics Physics Today. ,vol. 41, pp. 38- 45 ,(1988) , 10.1063/1.881127
A. W. Sleight, Chemistry of High-Temperature Superconductors Science. ,vol. 242, pp. 1519- 1527 ,(1988) , 10.1126/SCIENCE.242.4885.1519
Arndt Simon, Clusters of Valence Electron Poor Metals—Structure, Bonding, and Properties Angewandte Chemie International Edition in English. ,vol. 27, pp. 159- 183 ,(1988) , 10.1002/ANIE.198801591
Karl E. Spear, Diamond—Ceramic Coating of the Future Journal of the American Ceramic Society. ,vol. 72, pp. 171- 191 ,(1989) , 10.1111/J.1151-2916.1989.TB06099.X
J. Foise, K. Kim, J. Covino, K. Dwight, A. Wold, R. Chianelli, J Passeretti, Preparation and properties of the systems cobalt ruthenium sulfide (Co1-xRuxS2) and rhodium ruthenium sulfide (Rh1-xRuxS2) Inorganic Chemistry. ,vol. 14, pp. 61- 63 ,(1983) , 10.1021/IC00143A015