Synthesis, Crystal Structure and Magnetic Property of Double μ6-CO32− Centered Nonanuclear Ni(II) Cluster
作者： Cui Cui Wang , Hai Ye Li , Xiao Qiang Zhang , Yi Min Jiang , Shu Hua Zhang
DOI: 10.1007/S10876-014-0796-Z
关键词: Nickel 、 Crystallography 、 Chemistry 、 Catalysis 、 Antiferromagnetism 、 Nanochemistry 、 Ligand 、 Crystal structure 、 Single Crystal Diffraction 、 Cluster (physics)
摘要: A novel nonanuclear nickel cluster [Ni9(HL)6(μ 3-OH)6(μ 6-CO3)2(H2O)6]·3H2O·(OH)2(1) (H2L=3-(Pyridine-3-sulfonylamino)-propionic acid) has been synthesized and structurally determined by elemental analysis, IR, X-ray single crystal diffraction. Complex 1 consists of a (II) cage with double μ 6-CO3 2− bridge ant it represents the first whit HL ligand. Magnetic studies indicated that 6-CO3)2(H2O)6]2+ core displays dominant antiferromagnetic interaction between ions.
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