Atomic Electric Field Gradients of Five‐Electron Ions
作者： Oscar R. Platas
DOI: 10.1063/1.1733101
关键词: Ion 、 Atom 、 Fine structure 、 Energy (signal processing) 、 Electron 、 Atomic physics 、 Wave function 、 Electric field gradient 、 Chemistry 、 Electric field 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: The electric field gradient (∂2V/∂Z2)atom has been evaluated for BI, CII, NIII, OIV, FV, NeVI with an open‐configuration wavefunction the 2P state. fine structure splitting separation δ is calculated using computed values of and energy optimized orbital exponents 2p electron. BI agrees satisfactorily previous value obtained from observed levels. use a relativistic correction on which minimizes error in comparison experiment investigated.
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